典型文献
Electrospun carbon nanofibers for lithium metal anodes:Progress and perspectives
文献摘要:
Li metal anodes (LMAs) has attracted extensive research interest because of its extremely high theoretical capacity (3860 mAh/g) at low redox potential (-3.04 V vs.standard hydrogen electrode).However,the extremely high chemical reactivity and the intrinsic "hostless" nature of LMAs bring about serious den-dritic growth and dramatic volume change during the plating/strapping process,thus resulting in poor Coulombic efficiency,short lifespan,and severe safety concerns.Of various strategies,the construction of three-dimensional carbonaceous scaffolds for LMAs can substantially reduce the local current density,inhibit Li dendrite growth,and accommodate volume variation.Electrospinning is a simple yet effec-tive strategy to fabricate carbon nanofibers (CNFs),which have been regarded as promising skeletons for LMAs,owing to their large surface areas,good electrical conductivity,and high porosity.In this Mini Re-view,we briefly introduce the fabrication of CNFs using electrospinning and the modification of CNFs.We highlight the recent advances in electrospun CNF skeletons for LMAs,including pure CNF and CNF-based composite scaffolds.Finally,we discuss the remaining challenges of electrospun CNF scaffolds for LMAs and provide possible solutions to push forward the advancement in this field.
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中图分类号:
作者姓名:
Hongyang Chen;Manxian Li;Chuanping Li;Xuan Li;Yaling Wu;Xiaochuan Chen;Junxiong Wu;Xiaoyan Li;Yuming Chen
作者机构:
College of Environmental Science and Engineering,Fujian Normal University,Fuzhou 350007,China;College of Life Science,Fujian Normal University,Fuzhou 350007,China;School of Chemistry,Sun Yat-Sen University,Guangzhou 510275,China;State Key Laboratory of Structural Chemistry,Fuzhou 350000,China
文献出处:
引用格式:
[1]Hongyang Chen;Manxian Li;Chuanping Li;Xuan Li;Yaling Wu;Xiaochuan Chen;Junxiong Wu;Xiaoyan Li;Yuming Chen-.Electrospun carbon nanofibers for lithium metal anodes:Progress and perspectives)[J].中国化学快报(英文版),2022(01):141-152
A类:
hostless
B类:
Electrospun,nanofibers,lithium,metal,anodes,Progress,perspectives,Li,LMAs,has,attracted,extensive,research,interest,because,its,extremely,theoretical,capacity,mAh,low,redox,potential,standard,hydrogen,electrode,However,chemical,reactivity,intrinsic,nature,bring,about,serious,dritic,growth,dramatic,volume,change,during,plating,strapping,process,thus,resulting,poor,Coulombic,efficiency,short,lifespan,severe,safety,concerns,Of,various,strategies,construction,three,dimensional,carbonaceous,scaffolds,can,substantially,reduce,local,current,density,inhibit,dendrite,accommodate,variation,Electrospinning,simple,yet,effec,strategy,fabricate,CNFs,which,have,been,regarded,promising,skeletons,owing,their,large,surface,areas,good,electrical,conductivity,porosity,In,this,Mini,Re,view,briefly,introduce,fabrication,using,electrospinning,modification,We,highlight,recent,advances,electrospun,including,pure,composite,Finally,discuss,remaining,challenges,provide,possible,solutions,push,forward,advancement,field
AB值:
0.678064
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