典型文献
Synergistic stabilization of CsPbI3 inorganic perovskite via 1D capping and secondary growth
文献摘要：
Cesium lead iodide(CsPbI3)perovskite has gained great attention in the photovoltaic(PV)community because of its unique optoelectronic properties,good chemical stability and appropriate bandgap for sun-light harvesting applications.However,compared to solar cells fabricated from organic-inorganic hybrid perovskites,the commercialization of devices based on all-inorganic CsPbI3 perovskites still faces many challenges regarding PV performance and long-term stability.In this work,we discovered that tetrabuty-lammonium bromide(TBABr)post-treatment to CsPbI3 perovskite films could achieve synergistic stabi-lization with both TBA+cation intercalation and Br-doping.Such TBA+cation intercalation leads to one-dimensional capping with TBAPbI3 perovskite formed in situ,while the Br-induced crystal secondary growth helps effectively passivate the defects of CsPbI3 perovskite,thus enhancing the stability.In addi-tion,the incorporation of TBABr can improve energy-level alignment and reduce interfacial charge recombination loss for better device performance.Finally,the highly stable TBABr-treated CsPbI3-based perovskite solar cells show reproducible photovoltaic performance with a champion efficiency up to 19.04％,while retaining 90％of the initial efficiency after 500 h storage without encapsulation.
文献关键词：
中图分类号：
作者姓名：
Jingya Mi;Yuetian Chen;Xiaomin Liu;Xingtao Wang;Yanfeng Miao;Yabing Qi;Yixin Zhao
作者机构：
China-UK Low Carbon College,Shanghai Jiao Tong University,Shanghai 201306,China;School of Environmental Science and Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University,Shanghai 200240,China;Energy Materials and Surface Sciences Unit(EMSSU),Okinawa Institute of Science and Technology Graduate University(OIST),Okinawa 904-0495,Japan
文献出处：
引用格式：
[1]Jingya Mi;Yuetian Chen;Xiaomin Liu;Xingtao Wang;Yanfeng Miao;Yabing Qi;Yixin Zhao-.Synergistic stabilization of CsPbI3 inorganic perovskite via 1D capping and secondary growth)[J].能源化学,2022(05):387-392
A类：
tetrabuty,lammonium,TBABr,TBA+cation,TBAPbI3
B类：
Synergistic,stabilization,CsPbI3,inorganic,via,1D,capping,secondary,growth,Cesium,iodide,has,gained,great,attention,photovoltaic,PV,community,because,its,unique,optoelectronic,properties,good,chemical,stability,appropriate,bandgap,sun,light,harvesting,applications,However,compared,solar,cells,fabricated,from,hybrid,perovskites,commercialization,devices,still,faces,many,challenges,regarding,performance,long,term,In,this,work,discovered,that,bromide,post,treatment,films,could,achieve,synergistic,both,intercalation,doping,Such,leads,one,dimensional,formed,situ,while,induced,crystal,helps,effectively,passivate,defects,thus,enhancing,addi,incorporation,can,improve,energy,level,alignment,reduce,interfacial,charge,recombination,loss,better,Finally,highly,stable,treated,show,reproducible,champion,efficiency,up,retaining,initial,after,storage,without,encapsulation
AB值：
0.585536
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