典型文献
Selective Electrocatalytic Hydrogenation of 5-Hydroxymethyl-furfural to 2,5-Dihydroxymethylfuran on Bimetallic PdCu Alloy
文献摘要：
2,5-dihydroxymethylfuran(DHMF),obtained from 5-hydroxymethylfurfural(HMF)by electrochemical method,is a promising building block for polymers.However,one challenge of this process is to reduce initial potential and improve catalytic selec-tivity.In this work,the PdCu bimetallic catalyst is prepared with an onset potential of-0.05 VRHE and a selectivity of 99％.Compared with the single Cu electrocatalyst,the adsorption of HMF and proton is improved by introducing of Pd,which is demonstrated by the electrochemical results and hydrogen production rate.This work provides an ef-fective strategy to improve the selectivity of Cu-based electrocatalyst and builds a rela-tionship between the adsorption capacity and the electrocatalytic performance.
文献关键词：
中图分类号：
作者姓名：
Xu Yue;Weixing Zhao;Shuangyin Wang;Yuqin Zou
作者机构：
State Key Laboratory of Chem/Bio-Sensing and Chemometrics,College of Chemistry and Chemical Engineering,Advanced Catalytic Engineering Research Center of the Ministry of Education,Hunan University,Changsha 410082,China;Shenzhen Institute of Hunan University,Shenzhen 518057,China
文献出处：
引用格式：
[1]Xu Yue;Weixing Zhao;Shuangyin Wang;Yuqin Zou-.Selective Electrocatalytic Hydrogenation of 5-Hydroxymethyl-furfural to 2,5-Dihydroxymethylfuran on Bimetallic PdCu Alloy)[J].结构化学,2022(05):63-69
A类：
Hydroxymethyl,Dihydroxymethylfuran,dihydroxymethylfuran,DHMF
B类：
Selective,Electrocatalytic,Hydrogenation,Bimetallic,PdCu,Alloy,obtained,from,hydroxymethylfurfural,by,electrochemical,method,promising,building,block,polymers,However,one,challenge,this,process,reduce,initial,potential,In,work,bimetallic,prepared,onset,VRHE,selectivity,Compared,single,electrocatalyst,adsorption,proton,improved,introducing,which,demonstrated,results,hydrogen,production,This,provides,ef,fective,strategy,builds,rela,tionship,between,capacity,electrocatalytic,performance
AB值：
0.541108
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