典型文献
Atomically Dispersed Fe-Co Bimetallic Catalysts for the Promoted Electroreduction of Carbon Dioxide
文献摘要：
The electroreduction reaction of CO2 (ECO2RR) requires high-performance catalysts to convert CO2 into useful chemicals.Tran-sition metal-based atomically dispersed catalysts are promising for the high selectivity and activity in ECO2RR.This work presents a series of atomically dispersed Co,Fe bimetallic catalysts by carbonizing the Fe-introduced Co-zeolitic-imidazolate-framework (C-Fe-Co-ZIF)for the syngas generation from ECO2RR.The synergistic effect of the bimetallic catalyst promotes CO production.Compared to the pure C-Co-ZIF,C-Fe-Co-ZIF facilitates CO production with a CO Faradaic efficiency (FE) boost of 10％,with optimal FECO of 51.9％,FEH2 of 42.4％ at-0.55 V,and CO current density of 8.0 mA cm-2 at-0.7 V versus reversible hydrogen electrode (RHE).The H2/CO ratio is tunable from 0.8 to 4.2 in a wide potential window of-0.35 to-0.8 V versus RHE.The total FECO+H2 maintains as high as 93％ over 10 h.The proper adding amount of Fe could increase the number of active sites and create mild distortions for the nanoscopic environments of Co and Fe,which is essential for the enhancement of the CO produc-tion in ECO2RR.The positive impacts of Cu-Co and Ni-Co bimetallic catalysts demonstrate the versatility and potential application of the bimetallic strategy for ECO2RR.
文献关键词：
中图分类号：
作者姓名：
Zhangsen Chen;Gaixia Zhang;Yuren Wen;Ning Chen;Weifeng Chen;Tom Regier;James Dynes;Yi Zheng;Shuhui Sun
作者机构：
Institut National de la Recherche Scientifique-(E)nergie Matériaux et Télécommunications,Varennes,QC J3X 1P7,Canada;School of Materials Science and Engineering,University of Science and Technology,100083 Beijing,People's Republic of China;Canadian Light Source,University of Saskatchewan,Saskatoon,SK S7N 2V3,Canada;Research Institute of Photocatalysis,State Key Laboratory of Photocatalysis on Energy and Environment,Fuzhou University,Fuzhou 350116,People's Republic of China
文献出处：
引用格式：
[1]Zhangsen Chen;Gaixia Zhang;Yuren Wen;Ning Chen;Weifeng Chen;Tom Regier;James Dynes;Yi Zheng;Shuhui Sun-.Atomically Dispersed Fe-Co Bimetallic Catalysts for the Promoted Electroreduction of Carbon Dioxide)[J].纳微快报（英文）,2022(02):79-93
A类：
ECO2RR,FECO,FEH2,FECO+H2
B类：
Atomically,Dispersed,Bimetallic,Catalysts,Promoted,Electroreduction,Carbon,Dioxide,electroreduction,reaction,requires,high,performance,catalysts,convert,into,useful,chemicals,Tran,sition,atomically,dispersed,promising,selectivity,activity,This,presents,series,bimetallic,by,carbonizing,introduced,zeolitic,imidazolate,framework,ZIF,syngas,generation,from,synergistic,effect,promotes,production,Compared,pure,facilitates,Faradaic,efficiency,boost,optimal,current,density,mA,versus,reversible,hydrogen,electrode,RHE,tunable,wide,potential,window,total,maintains,over,proper,adding,amount,could,increase,number,active,sites,create,mild,distortions,nanoscopic,environments,which,essential,enhancement,positive,impacts,demonstrate,versatility,application,strategy
AB值：
0.52489
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