典型文献
Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery
文献摘要:
Room temperature sodium-sulfur(RT Na-S)battery with high theoretical energy density and low cost has spurred tremendous interest,which is recognized as an ideal candidate for large-scale energy storage applications.However,serious sodium polysulfide shutting and sluggish reaction kinetics lead to rapid capacity decay and poor Coulombic efficiency.Recently,catalytic materials capable of adsorbing and catalyzing the conversion of polysulfides are profiled as a promising method to improve electrochemical performance.In this review,the research progress is summarized that the application of catalytic materials in RT Na-S battery.For the role of catalyst on the conversion of sulfur species,specific attention is focused on the influence factors of reaction rate during different redox processes.Various catalytic materials based on lightweight and high conductive carbon materials,including heteroatom-doped carbon,metals and metal compounds,single-atom and heterostructure,promote the reaction kinetic via lowered energy barrier and accelerated charge transfer.Additionally,the adsorption capacity of the catalytic materials is the key to the catalytic effect.Particular attention to the interaction between polysulfides and sulfur host materials is necessary for the exploration of catalytic mechanism.Lastly,the challenges and outlooks toward the desired design of efficient catalytic materials for RT Na-S battery are discussed.
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作者姓名:
Zhenzhen Yang;Ru Xiao;Xiaoyin Zhang;Xin Wang;Dong Zhang;Zhenhua Sun;Feng Li
作者机构:
Key Laboratory of Physics and Technology for Advanced Battery(Ministry of Education),College of Physics,Jilin University,Changchun 130012,China;Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;School of Materials Science and Engineering,University of Science and Technology of China,Shenyang 110016,China
文献出处:
引用格式:
[1]Zhenzhen Yang;Ru Xiao;Xiaoyin Zhang;Xin Wang;Dong Zhang;Zhenhua Sun;Feng Li-.Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery)[J].能源与环境材料(英文),2022(03):693-710
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AB值:
0.63616
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