典型文献
CO2 Reduction on Metal-Doped SnO2(110)Surface Catalysts:Manipulating the Product by Changing the Ratio of Sn∶O
文献摘要：
The electrocatalytic carbon dioxide reduction reac-tion(CO2RR)producing HCOOH and CO is one of the most promising approaches for storing renewable electricity as chemical energy in fuels.SnO2 is a good catalyst for CO2-to-HCOOH or CO2-to-CO conversion,with different crystal planes participating the catalytic process.Among them,(110)surface SnO2 is very stable and easy to synthesisze.By changing the ratio of Sn∶O for SnO2(110),we have two typical SnO2 thin films:fully oxidized(stoichiometric)and partially reduced.In this work,we are concerned with different metals(Fe,Co,Ni,Cu,Ru,Rh,Pd,Ag,Os,Ir,Pt,and Au)-doped SnO2(110)with different activity and selectivity for CO2RR.All these changes are manipulated by adjusting the ratio of Sn∶O in(110)surface.The results show that stochiometric and reduced Cu/Ag doped SnO2(110)have different selectivity for CO2RR.More specifically,stochiometric Cu/Ag-doped SnO2(110)tends to generate CO(g).Meanwhile,the reduced surface tends to generate HCOOH(g).Moreover,we also considered the competitive hydrogen evolution reaction(HER).The catalysts SnO2(110)doped by Ru,Rh,Pd,Os,Ir,and Pt have high activity for HER,and others are good catalysts for CO2RR.
文献关键词：
中图分类号：
作者姓名：
Lei Cui;DaDi Zhang;Yuan Kong;Xiao Zheng
作者机构：
Department of Chemical Physics and Hefei National Laboratory for Physical Sciences at the Mi-croscale,University of Science and Technology of China,Hefei 230026,China;National Synchrotron Radiation Laboratory,University of Science and Technology of China,Hefei 230029,China
文献出处：
引用格式：
[1]Lei Cui;DaDi Zhang;Yuan Kong;Xiao Zheng-.CO2 Reduction on Metal-Doped SnO2(110)Surface Catalysts:Manipulating the Product by Changing the Ratio of Sn∶O)[J].化学物理学报（英文版）,2022(03):413-421
A类：
synthesisze,stochiometric
B类：
Reduction,Metal,Doped,SnO2,Surface,Catalysts,Manipulating,Product,by,Changing,Ratio,electrocatalytic,carbon,dioxide,reduction,CO2RR,producing,HCOOH,one,most,promising,approaches,storing,renewable,electricity,chemical,energy,fuels,good,conversion,different,crystal,planes,participating,process,Among,them,surface,very,stable,easy,By,changing,ratio,we,have,two,typical,thin,films,fully,oxidized,stoichiometric,partially,reduced,In,this,work,are,concerned,metals,Co,Ru,Rh,Pd,Ag,Os,Ir,Pt,Au,doped,activity,selectivity,All,these,changes,manipulated,adjusting,results,show,that,specifically,tends,generate,Meanwhile,Moreover,also,considered,competitive,hydrogen,evolution,reaction,HER,catalysts,high,others
AB值：
0.518361
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