典型文献
Gold Self-Relay Catalysis Enabling[3,3]-Sigmatropic Rearrange-ment/Nazarov Cyclization and Allylic Alkylation Cascade for Constructing All-Carbon Quaternary Stereocenters
文献摘要：
Molecular scaffolds endowed with all-carbon quaternary stereocenter are ubiquitous in natural products and significant bioactive molecules.However,efficient construction of this type of structure units is full of challenge due to their congested chemical envi-ronment.Herein,we report a new gold(Ⅰ)self-relay catalysis merging[3,3]-sigmatropic rearrangement/Nazarov cyclization with al-lylic alkylation starting from 1,3-enyne acetates and allylic alcohols,producing a wide range of synthetically important allyl cyclo-pentenones with an all-carbon quaternary stereocenter in good yields under mild conditions.This protocol demonstrates the precise control of regioselectivity,high functional group tolerance of substrates and the low loading of gold catalyst without inert atmos-phere protection,providing a catalytic and efficient entry to all-carbon quaternary stereocenters
文献关键词：
中图分类号：
作者姓名：
Fan-Tao Meng;Xiao-Yan Qin;Jing Li;Tian-Shu Zhang;Shu-Jiang Tu;Bo Jiang;Wen-Juan Hao
作者机构：
School of Chemistry&Materials Science,Jiangsu Normal University,Xuzhou,Jiangsu 221116,China;School of Materials and Chemical Engineering,Xuzhou University of Technology,Xuzhou,Jiangsu 221018,China
文献出处：
引用格式：
[1]Fan-Tao Meng;Xiao-Yan Qin;Jing Li;Tian-Shu Zhang;Shu-Jiang Tu;Bo Jiang;Wen-Juan Hao-.Gold Self-Relay Catalysis Enabling[3,3]-Sigmatropic Rearrange-ment/Nazarov Cyclization and Allylic Alkylation Cascade for Constructing All-Carbon Quaternary Stereocenters)[J].中国化学（英文版）,2022(06):687-692
A类：
Sigmatropic,Rearrange,Nazarov,Cyclization,Allylic,Stereocenters,stereocenter,sigmatropic,lylic,enyne,acetates,pentenones,stereocenters
B类：
Gold,Self,Relay,Catalysis,Enabling,Alkylation,Cascade,Constructing,Carbon,Quaternary,Molecular,scaffolds,endowed,carbon,quaternary,are,ubiquitous,natural,products,significant,bioactive,molecules,However,efficient,construction,this,type,structure,units,full,challenge,due,their,congested,chemical,envi,ronment,Herein,report,new,gold,self,relay,catalysis,merging,rearrangement,cyclization,alkylation,starting,from,allylic,alcohols,producing,wide,synthetically,important,cyclo,good,yields,under,mild,conditions,This,protocol,demonstrates,precise,control,regioselectivity,high,functional,group,tolerance,substrates,low,loading,catalyst,without,inert,atmos,phere,protection,providing,catalytic,entry
AB值：
0.628578
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
