典型文献
Inner Co Synergizing Outer Ru Supported on Carbon Nanotubes for Efficient pH-Universal Hydrogen Evolution Catalysis
文献摘要：
Exploring highly active but inexpensive electrocatalysts for the hydrogen evolu-tion reaction(HER)is of critical importance for hydrogen production from electrochemical water splitting.Herein,we report a multicomponent catalyst with exceptional activity and durability for HER,in which cobalt nanoparticles were in-situ confined inside bamboo-like car-bon nanotubes(CNTs)while ultralow ruthenium loading(～2.6 μg per electrode area～cm-2)is uniformly deposited on their exterior walls(Co@CNTs|Ru).The atomic-scale structural investigations and theoretical calculations indicate that the confined inner Co and loaded outer Ru would induce charge redistribution and a synergistic electron coupling,not only optimiz-ing the adsorption energy of H intermediates(ΔGH*)but also facilitating the electron/mass transfer.The as-developed Co@CNTs|Ru composite catalyst requires overpotentials of only 10,32,and 63 mV to afford a current density of 10 mA cm-2 in alkaline,acidic and neutral media,respectively,representing top-level catalytic activity among all reported HER catalysts.The current work may open a new insight into the rational design of carbon-supported metal catalysts for practical applications.
文献关键词：
中图分类号：
作者姓名：
Jian Chen;Yuan Ha;Ruirui Wang;Yanxia Liu;Hongbin Xu;Bin Shang;Renbing Wu;Hongge Pan
作者机构：
Institute of Science and Technology for New Energy,Xi'an Technological University,Xi'an 710021,People's Republic of China;School of Advanced Materials and Nanotechnology,Xidian University,Xi'an 710126,People's Republic of China;Department of Materials Science,Fudan University,Shanghai 200433,People's Republic of China;State Key Laboratory of New Textile Materials and Advanced Processing Technologies,Wuhan Textile University,Wuhan 430073,People's Republic of China;State Key Laboratory of Silicon Materials and School of Materials Science and Engineering,Zhejiang University,Hangzhou 310027,People's Republic of China
文献出处：
引用格式：
[1]Jian Chen;Yuan Ha;Ruirui Wang;Yanxia Liu;Hongbin Xu;Bin Shang;Renbing Wu;Hongge Pan-.Inner Co Synergizing Outer Ru Supported on Carbon Nanotubes for Efficient pH-Universal Hydrogen Evolution Catalysis)[J].纳微快报（英文）,2022(11):275-289
A类：
Synergizing
B类：
Inner,Co,Outer,Ru,Supported,Carbon,Nanotubes,Efficient,Universal,Hydrogen,Evolution,Catalysis,Exploring,highly,active,inexpensive,electrocatalysts,hydrogen,evolu,reaction,HER,critical,importance,production,from,electrochemical,water,splitting,Herein,multicomponent,exceptional,activity,durability,which,cobalt,nanoparticles,were,situ,confined,inside,bamboo,like,nanotubes,CNTs,while,ultralow,ruthenium,loading,per,electrode,area,uniformly,deposited,their,exterior,walls,atomic,scale,structural,investigations,theoretical,calculations,indicate,that,inner,loaded,outer,would,induce,charge,redistribution,synergistic,electron,coupling,only,optimiz,adsorption,energy,intermediates,GH,also,facilitating,mass,transfer,developed,composite,requires,overpotentials,mV,afford,current,density,mA,alkaline,acidic,neutral,respectively,representing,top,level,catalytic,among,reported,work,may,open,new,insight,into,rational,design,carbon,supported,metal,practical,applications
AB值：
0.7119
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