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典型文献
Structural and optical properties evolution in pressure-induced amorphization of metal-organic framework ZIF-8
文献摘要:
Zeolitic imidazolate framework-8[ZIF-8],a metal-organic framework[MOF]with a non-centrosymmetric crystal structure,exhibits nonlinear optics[NLO]properties and can act as the nanoporous matrix of guest molecules.Amorphization of ZIF-8 can be achieved by pressure or high temperature.Both crystalline and amorphous states have their inherent features for optical applications.The effects of the crystalline-amorphous transition on the structural and optical properties under pressure were investigated in detail.Amorphization leads to the destruction of the ZIF-8 lattice structure,collapse of pores,and the change of spatial symmetry,which in turn alters the NLO properties of ZIF-8 and the luminescence properties of the guest Eu cations.Our results establish the structure-optical properties relationship in the amorphization process and provide new clues in designing novel MOFs optical materials.
文献关键词:
作者姓名:
Xin Huang;Jin He;Yiguang Jiang;Zhuocheng Chen;Xing Duan;Long Zhang
作者机构:
CAS Key Laboratory of Materials for High Power Laser,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China;College of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences[UCAS],Beijing 100049,China;Hangzhou Institute for Advanced Study,UCAS,Hangzhou 310024,China;School of Materials and Chemistry,University of Shanghai for Science and Technology,Shanghai 200093,China;Center of Advanced Optoelectronic Materials and Devices,Key Laboratory of Novel Materials for Sensor of Zhejiang Province,College of Materials and Environmental Engineering,Hangzhou Dianzi University,Hangzhou 310018,China;Collaborative Innovation Center of IFSA[CICIFSA],Shanghai Jiao Tong University,Shanghai 200240,China
引用格式:
[1]Xin Huang;Jin He;Yiguang Jiang;Zhuocheng Chen;Xing Duan;Long Zhang-.Structural and optical properties evolution in pressure-induced amorphization of metal-organic framework ZIF-8)[J].中国光学快报(英文版),2022(09):49-54
A类:
Amorphization
B类:
Structural,optical,properties,evolution,pressure,induced,amorphization,metal,organic,framework,ZIF,Zeolitic,imidazolate,centrosymmetric,structure,exhibits,nonlinear,optics,NLO,can,act,as,nanoporous,matrix,guest,molecules,be,achieved,by,high,temperature,Both,crystalline,amorphous,states,have,their,inherent,features,applications,effects,transition,structural,under,were,investigated,detail,leads,destruction,lattice,collapse,pores,change,spatial,symmetry,which,turn,alters,luminescence,Eu,Our,results,establish,relationship,process,provide,new,clues,designing,novel,MOFs,materials
AB值:
0.586452
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