典型文献
Atomically precise metal chalcogenide supertetrahedral clusters:frameworks to molecules,and structure to function
文献摘要：
Metal chalcogenide supertetrahedral clusters (MCSCs) are of significance for developing crystalline porous framework materials and atomically precise cluster chemistry.Early research interest focused on the synthetic and structural chemistry of MCSC-based porous semiconductor materials with different cluster sizes/compositions and their applications in adsorption-based separation and optoelectronics.More recently,focus has shifted to the cluster chemistry of MCSCs to establish atomically precise structure-composition-property relationships,which are critical for regulating the properties and expanding the applications of MCSCs.Importantly,MCSCs are similar to Ⅱ-Ⅵ or Ⅰ-Ⅲ-Ⅵ semiconductor nanocrystals (also called quantum dots,QDs) but avoid their inherent size polydispersity and structural ambiguity.Thus,discrete MCSCs,especially those that are solution-processable,could provide models for understanding various issues that cannot be easily clarified using QDs.This review covers three decades of efforts on MCSCs,including advancements in MCSC-based open frameworks (reticular chemistry),the precise structure-property relationships of MCSCs (cluster chemistry),and the functionalization and applications ofMCSC-based microcrystals.An outlook on remaining problems to be solved and future trends is also presented.
文献关键词：
中图分类号：
作者姓名：
Jiaxu Zhang;Pingyun Feng;Xianhui Bu;Tao Wu
作者机构：
College of Chemistry,Chemical Engineering and Material Science,Soochow University,Suzhou 215123,China;Department of Chemistry,University of California,Riverside,CA 92521,USA;Department of Chemistry and Biochemistry,California State University,Long Beach,CA 90840,USA;College of Chemistry and Materials Science,Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications,Jinan University,Guangzhou 510632,China
文献出处：
引用格式：
[1]Jiaxu Zhang;Pingyun Feng;Xianhui Bu;Tao Wu-.Atomically precise metal chalcogenide supertetrahedral clusters:frameworks to molecules,and structure to function)[J].国家科学评论（英文版）,2022(01):123-138
A类：
supertetrahedral,MCSCs,MCSC,ofMCSC
B类：
Atomically,precise,metal,chalcogenide,clusters,frameworks,molecules,structure,Metal,are,significance,developing,crystalline,porous,materials,atomically,chemistry,Early,research,interest,focused,synthetic,structural,semiconductor,different,sizes,compositions,their,applications,adsorption,separation,optoelectronics,More,recently,has,shifted,establish,property,relationships,which,critical,regulating,properties,expanding,Importantly,similar,nanocrystals,also,called,quantum,dots,QDs,but,avoid,inherent,polydispersity,ambiguity,Thus,discrete,especially,those,that,solution,processable,could,provide,models,understanding,various,issues,cannot,be,easily,clarified,using,This,review,covers,three,decades,efforts,including,advancements,open,reticular,functionalization,microcrystals,An,outlook,remaining,problems,solved,future,trends,presented
AB值：
0.543179
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