典型文献
Structural and optical properties evolution in pressure-induced amorphization of metal-organic framework ZIF-8
文献摘要：
Zeolitic imidazolate framework-8 (ZIF-8), a metal-organic framework (MOF) with a non-centrosymmetric crystal structure, exhibits nonlinear optics (NLO) properties and can act as the nanoporous matrix of guest molecules. Amorphization of ZIF-8 can be achieved by pressure or high temperature. Both crystalline and amorphous states have their inherent features for optical applications. The effects of the crystalline-amorphous transition on the structural and optical properties under pressure were investigated in detail. Amorphization leads to the destruction of the ZIF-8 lattice structure, collapse of pores, and the change of spatial symmetry, which in turn alters the NLO properties of ZIF-8 and the luminescence properties of the guest Eu cations. Our results establish the structure–optical properties relationship in the amorphization process and provide new clues in designing novel MOFs optical materials.
文献关键词：
中图分类号：
作者姓名：
Xin Huang;Jin He;Yiguang Jiang;Zhuocheng Chen;Xing Duan;Long Zhang
作者机构：
CAS Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China;College of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences (UCAS), Beijing 100049, China;Hangzhou Institute for Advanced Study, UCAS, Hangzhou 310024, China;School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China;Center of Advanced Optoelectronic Materials and Devices, Key Laboratory of Novel Materials for Sensor of Zhejiang Province, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China;Collaborative Innovation Center of IFSA (CICIFSA), Shanghai Jiao Tong University, Shanghai 200240, China
文献出处：
引用格式：
[1]Xin Huang;Jin He;Yiguang Jiang;Zhuocheng Chen;Xing Duan;Long Zhang-.Structural and optical properties evolution in pressure-induced amorphization of metal-organic framework ZIF-8)[J].中国光学快报（英文版）,2022(09):091603
A类：
Amorphization
B类：
Structural,optical,properties,evolution,pressure,induced,amorphization,metal,organic,framework,ZIF,Zeolitic,imidazolate,centrosymmetric,structure,exhibits,nonlinear,optics,NLO,can,act,as,nanoporous,matrix,guest,molecules,be,achieved,by,high,temperature,Both,crystalline,amorphous,states,have,their,inherent,features,applications,effects,transition,structural,under,were,investigated,detail,leads,destruction,lattice,collapse,pores,change,spatial,symmetry,which,turn,alters,luminescence,Eu,Our,results,establish,relationship,process,provide,new,clues,designing,novel,MOFs,materials
AB值：
0.586452
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