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典型文献
Effect of boron on dissolution and repairing behavior of passive film on S31254 super-austenitic stainless steel immersed in H2S04 solution
文献摘要:
The impact of boron on the dissolution and repairing behavior of passive films formed on S31254 super-austenitic stainless steel(SASS)was investigated.SASS was immersed in 0.5 mol/L of H2SO4 for 0,2,6,10,and 14 days to explore the evolution of the passive film.The electrochemical impedance spectroscope(EIS),the Mott-Schottky analysis,and X-ray photoelectron spectroscope were utilized to analyze the semiconductor properties and compositions of the passive films.EIS showed a decrease and consequent increase over 14 days;the same pattern was observed for Cr2O3 and Cr/Fe.However,the defect density of the passive film exhibited a reverse trend.The variation in film thicknesses indicated that the passive films possessed dissolution and repairing behavior.SASS passive film had a double-layer structure;the outer layer was found to be rich in Fe3+and Cr(OH)3,but low on Mo6+,while the inner layer was rich in Cr2O3 and low in Mo4+.The addition of boron increased the corrosion resistance and could promote the efficiency of the passive film repair,likely by promoting the migration of Mox+,which promoted the repairing of the passive film.
文献关键词:
作者姓名:
Tong-hao Wang;Jian Wang;Jin-gang Bai;Shu-jing Wang;Chao Chen;Pei-de Han
作者机构:
School of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China;Technology Center,Shanxi Taigang Stainless Steel Co.,Ltd.,Taiyuan 030003,Shanxi,China
引用格式:
[1]Tong-hao Wang;Jian Wang;Jin-gang Bai;Shu-jing Wang;Chao Chen;Pei-de Han-.Effect of boron on dissolution and repairing behavior of passive film on S31254 super-austenitic stainless steel immersed in H2S04 solution)[J].钢铁研究学报(英文版),2022(06):1012-1025
A类:
Mox+
B类:
Effect,boron,dissolution,repairing,behavior,passive,S31254,super,austenitic,stainless,steel,immersed,H2S04,impact,films,formed,SASS,was,investigated,H2SO4,days,explore,evolution,electrochemical,impedance,spectroscope,EIS,Mott,Schottky,analysis,ray,photoelectron,were,utilized,analyze,semiconductor,properties,compositions,showed,decrease,consequent,over,same,pattern,observed,Cr2O3,However,defect,density,exhibited,reverse,trend,variation,thicknesses,indicated,that,possessed,had,double,layer,structure,outer,found,rich,Fe3+and,but,low,Mo6+,while,inner,Mo4+,addition,increased,corrosion,resistance,could,efficiency,likely,by,promoting,migration,which,promoted
AB值:
0.497617
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