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典型文献
Synthesis and optical properties of novel apatite-type NaCa3Bi(PO4)3F:Dy3+yellow-emitting fluorophosphate phosphors for white LEDs
文献摘要:
In this study,novel yellow-emitting fluorophosphate NaCa3Bi(PO4)3F phosphors doped with different concentrations of Dy3十 ions were first obtained via high-temperature solid-state reaction.The crystal structure,phase purity,particle morphology,photoluminescence(PL)properties,thermal stability,and luminescence decay curves of the resulting phosphors were then characterized in detail.Under the excitation of 349 nm,the three dominant peaks of the NaCa3Bi(PO4)3F:Dy3+are centered at 480 nm(4F9/2-6H15/2),577 nm(4F9/2-6H13/2),and 662 nm(4F9/2-6H11/2).The optimal doping concentration of Dy3+ions in the NaCa3Bi(PO4)3F:xDy3+phosphors is x=5 mol%.The phosphors show excellent thermal stability with high activation energy(Ea=0.32 eV).Eventually,the synthesized white light-emitting diode(w-LED)demonstrates the Commission International de L'Eclairage(CIE)chroma-ticity coordinates of(0.341,0.334),a good correlated color temperature(CCT)of 5083 K,and a high color rendering index(Ra)of 92.Revealing its potential as yellow-emitting phosphors,the feasibility of the fabricated apatite-type NaCa3Bi(PO4)3F:Dy3+fluorophosphate phosphors was confirmed for w-LEDs.
文献关键词:
作者姓名:
Yuan Wang;Guangliang Lu;Yang Qiu;Wen Sun;Siqi Qin;Yifang Lin;Bin Deng;Dan Zhang;Ruijin Yu
作者机构:
College of Science,Northwest A&F University,Yangling 712100,China;School of Chemistry and Environmental Science,Xiangnan University,Chenzhou 423043,China;Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds Research and Application,Xiangnan University,Chenzhou 423043,China;College of Chemistry&Pharmacy,Northwest A&F University,Yangling 712100,China;Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials,College of Materials and Chemical Engineering,China Three Gorges University,Yichang 443002,China
引用格式:
[1]Yuan Wang;Guangliang Lu;Yang Qiu;Wen Sun;Siqi Qin;Yifang Lin;Bin Deng;Dan Zhang;Ruijin Yu-.Synthesis and optical properties of novel apatite-type NaCa3Bi(PO4)3F:Dy3+yellow-emitting fluorophosphate phosphors for white LEDs)[J].稀土学报(英文版),2022(12):1827-1836
A类:
NaCa3Bi,Dy3+yellow,fluorophosphate,Dy3,Dy3+are,6H15,6H11,Dy3+ions,xDy3+phosphors,Dy3+fluorophosphate
B类:
Synthesis,optical,properties,novel,apatite,type,PO4,3F,emitting,white,LEDs,this,study,doped,different,concentrations,were,first,obtained,via,high,temperature,solid,state,reaction,crystal,structure,phase,purity,particle,morphology,photoluminescence,PL,thermal,stability,decay,curves,resulting,then,characterized,detail,Under,excitation,three,dominant,peaks,centered,4F9,6H13,optimal,doping,show,excellent,activation,energy,Ea,eV,Eventually,synthesized,light,diode,demonstrates,Commission,International,Eclairage,CIE,chroma,ticity,coordinates,good,correlated,color,CCT,rendering,Ra,Revealing,its,potential,feasibility,fabricated,was,confirmed
AB值:
0.470234
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