典型文献
Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials
文献摘要:
White-light-emitting diodes (WLEDs) possess many merits,such as high efficiency and stability.Devel-oping cost-effective,environmentally friendly,high-performance luminophores to achieve high-quality,full-spectrum,white lighting is of great importance to the construction and progress of WLEDs.in this work,solid-state,highly luminescent orange-emitting nanoclusters (MgCl2-Lys-Ag/Au NCs) were prepared via the salt-induced precipitation of Lys-Ag/Au NCs from solution,which showed a high absolute quan-tum yield of 44.5%.A cyan-emitting metal-organic framework (MOF)-like nanomaterial (named Fe@TAOH)was also prepared by the self-assembly of the coordination compound of Fe3+ and TAOH acted upon by H3PO4 via H-bonding and π-π stacking interactions,which showed an emission peak at 485 nm and an absolute quantum yield of 21.7%.The potential application of the two facile-synthesis,low toxicity,and highly luminescent materials in WLEDs was investigated.The WLEDs was constructed by coating pow-dered Fe@TAOH and MgCl2-Lys-Ag/Au NCs samples on commercial GaN LED chip with 365 nm emissions,and it exhibited acceptable white light characteristics with a CIE color coordinates and a color rendering index (CRI) of (0.28,0.34) and 79.6,respectively,implying good prospects in the field of WLEDs.
文献关键词:
中图分类号:
作者姓名:
Wenying Mi;Na Shao
作者机构:
College of Chemistry,Beijing Normal University,Beijing 100875,China
文献出处:
引用格式:
[1]Wenying Mi;Na Shao-.Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials)[J].中国化学快报(英文版),2022(01):298-303
A类:
TAOH
B类:
Orange,emitting,bimetallic,nanoclusters,combined,cyan,white,materials,White,diodes,WLEDs,possess,many,merits,such,efficiency,stability,Devel,oping,cost,effective,environmentally,friendly,performance,luminophores,achieve,quality,full,spectrum,lighting,great,importance,construction,progress,this,solid,state,highly,luminescent,orange,MgCl2,Lys,Ag,Au,NCs,were,prepared,via,salt,induced,precipitation,from,solution,which,showed,absolute,yield,organic,framework,MOF,like,nanomaterial,named,was,also,by,self,assembly,coordination,compound,Fe3+,acted,upon,H3PO4,bonding,stacking,interactions,peak,quantum,potential,application,two,facile,synthesis,low,toxicity,investigated,constructed,coating,pow,dered,samples,commercial,GaN,chip,emissions,exhibited,acceptable,characteristics,CIE,color,coordinates,rendering,CRI,respectively,implying,good,prospects,field
AB值:
0.579101
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