典型文献
Atropisomer-based construction of a new perylene diimide macrocycle as visible-light photocatalyst for selective sulfide oxidation
文献摘要：
By using a perylene diimine(PDI)syn-atropisomer as highly preorganized precursor,we successfully con-structed a visible-light-active organic macrocycle PDI-M.The formation of macrocyclic structure effec-tively avoids self-aggregation of PDI cores and enhances the absorption in visible region.As a photocata-lyst,PDI-M exhibits excellent activity on aerobic selective oxidation of sulfide into sulfoxide under visible light irradiation at room temperature.Mechanism studies show that both superoxide and singlet oxy-gen act as reactive oxygen species.This work provides a typical case toward the maximum utilization of photosensitive groups under mild conditions.
文献关键词：
中图分类号：
作者姓名：
Fei Yang;Miaomiao Zhen;Shanshan Wang;Wei Wei;Huan He;Yanqing Xu
作者机构：
Key Laboratory of Cluster Science,Ministry of Education of China,Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China;Test&Analysis Center of Shougang Technical Research Institute,Beijing 100043,China;Department of Chemistry,Capital Normal University,Beijing 100048,China
文献出处：
引用格式：
[1]Fei Yang;Miaomiao Zhen;Shanshan Wang;Wei Wei;Huan He;Yanqing Xu-.Atropisomer-based construction of a new perylene diimide macrocycle as visible-light photocatalyst for selective sulfide oxidation)[J].中国化学快报（英文版）,2022(12):5088-5091
A类：
Atropisomer,macrocycle,diimine,atropisomer,preorganized
B类：
construction,new,perylene,diimide,visible,light,photocatalyst,selective,sulfide,oxidation,By,using,PDI,syn,highly,precursor,we,successfully,structed,organic,formation,macrocyclic,structure,effec,tively,avoids,self,aggregation,cores,enhances,absorption,region,exhibits,excellent,activity,aerobic,into,sulfoxide,under,irradiation,room,temperature,Mechanism,studies,show,that,both,superoxide,singlet,reactive,oxygen,species,This,work,provides,typical,case,toward,maximum,utilization,photosensitive,groups,mild,conditions
AB值：
0.598424
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
