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典型文献
Facile one-pot hydrothermal method to prepare Sn(Ⅱ) and N co-doped TiO2 photocatalyst for water splitting under visible light irradiation
文献摘要:
In this paper,a visible light-responsive Sn2+and N co-doped TiO2 photocatalyst was prepared by facile one-pot hydrothermal method.All as-prepared samples were characterized in detail by a series of characterization approaches.The results showed that the Sn2+ and N ele-ments were co-doped into TiO2,while the catalyst still maintains anatase crystal structure and gets irregular little nanocluster in diameter of 9-10 nm with higher specific surface area.The absorption edge of Sn2+ and N co-doped TiO2 extends to the visible light region.Compared with Sn2+-doped TiO2 and N-TiO2,the absorption edges have obvious red-shift of about 50 and 70 nm,respectively.The synergistic effect of O 2p-N 2p and O 2p-Sn 5s hybridization to form impurity levels is the main reason for the red-shift.The hydrogen production performance of the Sn2+ and N co-doping TiO2 (n(N)/n(Ti)=1) catalyst reached the maximum value of 0.37 mmol·h-1·g-1 under visible light,which is higher than that of N-doped TiO2 and Sn2+-doped TiO2 singly.This result is due to the wider visible light region-responsive ability of Sn2+ and N co-doped into TiO2.Furthermore,mild hydrothermal methods will not make the Sn2+ oxidized to Sn4+,which make the catalysts still maintain high photocatalytic performance.This work provides a simple and mild method for the preparation of dual-element co-doped TiO2 with high crystallinity,excellent performance and broad application prospects.
文献关键词:
作者姓名:
Xiao-Huan Jiang;Ying-Nan Duan;Yu Tian;Meng Chen;Mao-Kun Li;Huan-Huan Liu;Wan-Liang Yang;Meng-Kui Tian
作者机构:
School of Chemistry and Chemical Engineering,Guizhou University,Guiyang 550025,China
引用格式:
[1]Xiao-Huan Jiang;Ying-Nan Duan;Yu Tian;Meng Chen;Mao-Kun Li;Huan-Huan Liu;Wan-Liang Yang;Meng-Kui Tian-.Facile one-pot hydrothermal method to prepare Sn(Ⅱ) and N co-doped TiO2 photocatalyst for water splitting under visible light irradiation)[J].稀有金属(英文版),2022(02):406-414
A类:
Sn2+and
B类:
Facile,one,pot,hydrothermal,co,doped,TiO2,photocatalyst,water,splitting,under,visible,light,irradiation,In,this,paper,responsive,was,prepared,by,facile,All,samples,were,characterized,detail,series,characterization,approaches,results,showed,that,ments,into,while,still,maintains,anatase,structure,gets,irregular,little,nanocluster,diameter,higher,specific,surface,area,absorption,extends,region,Compared,edges,have,obvious,shift,about,respectively,synergistic,effect,2p,5s,hybridization,impurity,levels,reason,hydrogen,production,performance,doping,reached,maximum,value,which,than,singly,This,due,wider,ability,Furthermore,mild,methods,will,not,make,oxidized,Sn4+,catalysts,photocatalytic,work,provides,simple,preparation,dual,element,crystallinity,excellent,broad,application,prospects
AB值:
0.480787
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