典型文献
Transition metal-catalyzed conversion of aldehydes to ketones
文献摘要:
Ketones are one of the most important classes of organic compounds,and widely present in various pharmacological compounds,biologically active molecules and functional materials.Over the past few decades,transition metal-catalyzed conversion of aldehydes has been found to be a powerful method.With the continuous development in recent years,it has become an efficient and uncomplicated strategy for constructing ketones.There are four major mechanisms for transition metal-catalyzed ketone synthe-sis from aldehyde:(1)carbonyl-Heck reaction,that is 1,2-insertion of organometal species to aldehydic C=O double bond,(2)direct insertion of transition metal catalysts to aldehydic C-H bond,(3)aldehyde as acyl radical,(4)aldehyde as carbon radical acceptor.This article summarizes related reports on the transformations of aldehydes to generate corresponding ketones under different reaction conditions.
文献关键词:
中图分类号:
作者姓名:
Zijuan Yan;Pan-Lin Shao;Qing Qiang;Feipeng Liu;Xuchao Wang;Yongjie Li;Zi-Qiang Rong
作者机构:
Frontiers Science Center for Flexible Electronics(FSCFE),Shaanxi Institute of Flexible Electronics(SIFE)&Shaanxi Institute of Biomedical Materials and Engineering(SIBME),Northwestern Polytechnical University(NPU),Xi'an 710072,China;College of Innovation and Entrepreneurship,Southern University of Science and Technology,Shenzhen 518055,China
文献出处:
引用格式:
[1]Zijuan Yan;Pan-Lin Shao;Qing Qiang;Feipeng Liu;Xuchao Wang;Yongjie Li;Zi-Qiang Rong-.Transition metal-catalyzed conversion of aldehydes to ketones)[J].中国化学快报(英文版),2022(03):1207-1226
A类:
aldehydic
B类:
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AB值:
0.605834
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