典型文献
Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms:kinetics and reaction mechanism
文献摘要：
The reaction of Cl atoms with two Cs aldehydes(3-methyl-2-butenal and 3-methylbutanal)were investigated by proton-transfer-reaction mass spectrum(PTR-MS)using smog cham-ber at 298±1 K and 760 Torr.A relative rate method was used to determine the rate con-stants of the title reactions with m-xylene and trans-2-butene as reference compounds:(3.04±0.18)×10-10 and(2.07±0.14)×10-10 cm3/(molecule·sec)for 3-methyl-2-butenal and 3-methylbutanal,respectively.Additionally,the gas-phase products were also identi-fied by PTR-MS,and the possible reaction mechanisms were proposed basing on the identi-fied products.The detected gas-phase products are similar for two C5 aldehydes reactions,mainly including small molecules of aldehydes,ketones and chlorinated aldehyde com-pounds.The atmospheric lifetimes(τ)calculated for 3-methyl-2-butenal(τ=7.0 hr,marine boundary layer(MBL))and 3-methylbutanal(τ=10.3 hr,MBL)according to the obtained rate constants.The results indicate that Cl atoms at MBL are competitive with OH radicals for the degradation contribution of C5 aldehyde compounds.
文献关键词：
中图分类号：
作者姓名：
Bo Shi;Weigang Wang;Cici Fan;Yuchan Zhang;Zheng Sun;Yanli Zeng;Maofa Ge
作者机构：
College of Chemistry and Material Sciences,Hebei Normal University,Shijiazhuang 050024,China;National Demonstration Center for Experiment Chemistry,Hebei Normal University,Shijiazhuang 050024,China;Key Laboratory of Inorganic Nano-material of Hebei Province,Shijiazhuang 050024,China;State Key Laboratory for Structural Chemistry of Unstable and Stable Species,Beijing National Laboratory for Molecular Sciences(BNLMS),Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China;Lanfang Normal University,Langfang 065000,China
文献出处：
引用格式：
[1]Bo Shi;Weigang Wang;Cici Fan;Yuchan Zhang;Zheng Sun;Yanli Zeng;Maofa Ge-.Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms:kinetics and reaction mechanism)[J].环境科学学报（英文版）,2022(06):25-33
A类：
butenal,methylbutanal
B类：
Study,Cl,atoms,kinetics,two,Cs,aldehydes,were,investigated,by,proton,transfer,mass,spectrum,PTR,using,smog,cham,ber,Torr,relative,rate,method,was,used,determine,title,reactions,xylene,butene,reference,compounds,cm3,sec,respectively,Additionally,gas,phase,products,also,identi,fied,possible,mechanisms,proposed,basing,detected,are,similar,C5,mainly,including,small,molecules,ketones,chlorinated,atmospheric,lifetimes,calculated,hr,marine,boundary,layer,MBL,according,obtained,constants,results,indicate,that,competitive,radicals,degradation,contribution
AB值：
0.485729
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