典型文献
Biomass-based N doped carbon as metal-free catalyst for selective oxidation of D-xylose into D-xylonic acid
文献摘要：
Rational design and facile preparation of low-cost and efficient catalysts for the selective converting of biomass-derived monosaccharides into high value-added chemicals is highly demanded,yet challenging.Herein,we first demonstrate a N doped defect-rich carbon(NC-800-5)as metal-free catalyst for the selective oxidation of D-xylose into D-xylonic acid in alkaline aqueous solution at 100℃for 30 min,with 57.4％yield.The doped graphitic N is found to be the active site and hydroxyl ion participating in the oxidation of D-xylose.Hydroxyl ion and D-xylose first adsorb on NC-800-5 surface,and the aldehyde group of D-xylose is catalyzed to form germinal diols ion.Then,C-H bond break to yield carboxylic group.Furthermore,NC-800-5 catalyst shows high stability in recycled test.
文献关键词：
中图分类号：
作者姓名：
Zengyong Li;Yiming Huang;Xiao Chi;Di Li;Linxin Zhong;Xuehui Li;Chuanfu Liu;Xinwen Peng
作者机构：
State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou,510640,China;School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou,510640,China
文献出处：
引用格式：
[1]Zengyong Li;Yiming Huang;Xiao Chi;Di Li;Linxin Zhong;Xuehui Li;Chuanfu Liu;Xinwen Peng-.Biomass-based N doped carbon as metal-free catalyst for selective oxidation of D-xylose into D-xylonic acid)[J].绿色能源与环境（英文）,2022(06):1310-1317
A类：
xylonic
B类：
Biomass,doped,carbon,metal,free,selective,oxidation,xylose,into,acid,Rational,design,facile,preparation,low,cost,efficient,catalysts,converting,biomass,derived,monosaccharides,value,added,chemicals,is,highly,demanded,yet,challenging,Herein,we,first,demonstrate,defect,rich,NC,alkaline,aqueous,solution,yield,graphitic,found,be,active,site,hydroxyl,participating,Hydroxyl,adsorb,surface,aldehyde,group,catalyzed,form,germinal,diols,Then,bond,break,carboxylic,Furthermore,shows,stability,recycled,test
AB值：
0.577003
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
