典型文献
A β-cyclodextrin covalent organic framework used as a chiral stationary phase for chiral separation in gas chromatography
文献摘要：
Chiral covalent organic frameworks(CCOFs)featuring chirality,stability,and good porosity have attracted a considerable amount of attention due to their important applications,such as asymmetric catalysis,chi-ral separation,and chiral recognition.In this study,a β-cyclodextrin(β-CD)covalent organic framework(β-CD-COF)diluted with polysiloxane OV-1701 was explored as a novel chiral stationary phase(CSP)for gas chromatography(GC)separation of racemates.The β-CD-COF coated capillary column had excellent selectivity,not only for the separation of linear alkanes,linear alcohols,fatty acid methyl esters mix-ture,the Grob mixture and positional isomers,but also for the resolution of chiral compounds,including chiral alcohols,aldehydes,ethers,and amino acid derivatives.In addition,the β-CD-COF-coated capillary column presented good repeatability and reproducibility.This work indicated the great potential of the CCOFs coated capillary column for the chromatographic separation of enantiomers.
文献关键词：
中图分类号：
作者姓名：
Bo Tang;Wei Wang;Huipeng Hou;Yiquan Liu;Zongkun Liu;Lina Geng;Liquan Sun;Aiqin Luo
作者机构：
Key Laboratory of Molecular Medicine and Biotherapy,School of Life Science,Beijing Institute of Technology,Beijing 100081,China
文献出处：
引用格式：
[1]Bo Tang;Wei Wang;Huipeng Hou;Yiquan Liu;Zongkun Liu;Lina Geng;Liquan Sun;Aiqin Luo-.A β-cyclodextrin covalent organic framework used as a chiral stationary phase for chiral separation in gas chromatography)[J].中国化学快报（英文版）,2022(02):898-902
A类：
racemates,Grob
B类：
cyclodextrin,covalent,organic,used,stationary,phase,separation,gas,chromatography,Chiral,frameworks,CCOFs,featuring,chirality,stability,good,porosity,have,attracted,considerable,amount,attention,due,their,important,applications,such,asymmetric,catalysis,recognition,In,this,study,CD,diluted,polysiloxane,OV,was,explored,novel,CSP,coated,capillary,column,had,excellent,selectivity,not,only,linear,alkanes,alcohols,fatty,acid,methyl,esters,mixture,positional,isomers,but,also,resolution,compounds,including,aldehydes,ethers,amino,derivatives,addition,presented,repeatability,reproducibility,This,indicated,great,potential,chromatographic,enantiomers
AB值：
0.552619
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
