典型文献
A universal ionic liquid solvent for non-halide lead sources in perovskite solar cells
文献摘要：
Replacing lead iodide(Pbl2)with suitable non-halides lead source has been found to be an effective method to control crystallization and fabricate high-performance perovskite solar cells(PSCs).However,the solubility of non-halide lead sources is highly limited by traditional solvents due to the chemical interaction limitation.Here,we report a series of non-halide lead sources(e.g.,lead acetate(PbAc2),lead sulfate(PbSO4),lead carbonate(PbCO3),lead nitrate(Pb(NO3)2),lead formate(Pb(HCOO)2)and lead oxalate(PbC2O4))can be well dissolved in an ionic liquid solvent methylammonium acetate(MAAc).We found that the universal strong coordination of C=O with lead ion(Pb2+)and the for-mation of hydrogen bonds were observed in perovskite precursor solution.This allows the dissolution of non-halide lead salts and is able to produce perovskite film with smooth,compact,and full coverage crys-tal grain.The power conversion efficiency(PCE)of 14.48％,19.21％,and 20.13％in PSCs based on PbSO4,PbAc2,and PbCO3 was achieved,respectively,in the absence of any additives and passivation agents.This study demonstrates the universality of ionic liquid for the preparation of PSCs based on non-halides lead sources.
文献关键词：
中图分类号：
作者姓名：
Yue Chen;Yamin Xu;Jin Liu;Yuexin Lin;Jianfei Hu;Chensi Cao;Yingdong Xia;Yonghua Chen
作者机构：
Key Laboratory of Flexible Electronics(KLOFE)and Institute of Advanced Materials(IAM),Nanjing Tech University,Nanjing 211816,Jiangsu,China
文献出处：
引用格式：
[1]Yue Chen;Yamin Xu;Jin Liu;Yuexin Lin;Jianfei Hu;Chensi Cao;Yingdong Xia;Yonghua Chen-.A universal ionic liquid solvent for non-halide lead sources in perovskite solar cells)[J].能源化学,2022(08):445-451
A类：
Pbl2,PbAc2,PbC2O4
B类：
ionic,liquid,lead,sources,perovskite,solar,cells,Replacing,iodide,suitable,halides,has,been,found,effective,method,control,crystallization,fabricate,performance,PSCs,However,solubility,highly,limited,by,traditional,solvents,due,chemical,interaction,limitation,Here,report,series,acetate,sulfate,PbSO4,carbonate,PbCO3,nitrate,NO3,formate,HCOO,oxalate,can,well,dissolved,methylammonium,MAAc,We,that,strong,coordination,Pb2+,mation,hydrogen,bonds,were,observed,precursor,This,allows,dissolution,salts,produce,film,smooth,compact,full,coverage,grain,power,conversion,efficiency,PCE,was,achieved,respectively,absence,any,additives,passivation,agents,study,demonstrates,universality,preparation
AB值：
0.508038
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
