典型文献
Host-guest supramolecular interaction behavior at the interface between anode and electrolyte for long life Zn anode
文献摘要：
The hydrogen evolution reaction(HER)and dendrite growth associated with Zn anode have become the main bottlenecks for the further development of zinc ion batteries(ZIBs).In this work,the electrochem-ical activity of H3O+is inhibited by the supramolecular host-guest complex composed of H3O+as guest and 18-crown-6 as host.The even Zn plating is induced by the host-guest complex electrostatic shielding layer on Zn anode,as detected by in-situ optical microscopy.The lamellar Zn is plated which profits from the improved Zn plating behavior.Density functional theory(DFT)calculation presents the stable struc-ture of complex.The less produced H2 content is monitored online by a mass spectrometer during Zn plating/stripping,which indicates HER can be hampered by the host-guest behavior.Thus,the ZIBs with long life and high Coulombic efficiency are achieved via introducing 18-crown-6.The proposed host-guest supramolecular interaction is expected to facilitate the furthermore development of Zn batteries.
文献关键词：
中图分类号：
作者姓名：
Kai Wu;Fanghua Ning;Jin Yi;Xiaoyu Liu;Jiaqian Qin;Yuyu Liu;Jiujun Zhang
作者机构：
Institute for Sustainable Energy/College of Sciences,Shanghai University,Shanghai 200444,China;Center of Excellence in Responsive Wearable Materials,Metallurgy and Materials Science Research Institute,Chulalongkorn University,Bangkok 10330,Thailand
文献出处：
引用格式：
[1]Kai Wu;Fanghua Ning;Jin Yi;Xiaoyu Liu;Jiaqian Qin;Yuyu Liu;Jiujun Zhang-.Host-guest supramolecular interaction behavior at the interface between anode and electrolyte for long life Zn anode)[J].能源化学,2022(06):237-243
A类：
H3O+is,H3O+as
B类：
Host,guest,supramolecular,interaction,behavior,interface,between,anode,electrolyte,long,life,hydrogen,evolution,reaction,HER,dendrite,growth,associated,have,become,main,bottlenecks,development,zinc,batteries,ZIBs,In,this,work,electrochem,activity,inhibited,by,host,complex,composed,crown,even,plating,induced,electrostatic,shielding,layer,detected,situ,optical,microscopy,lamellar,plated,which,profits,from,improved,Density,functional,theory,DFT,calculation,presents,stable,struc,ture,less,produced,H2,content,monitored,online,mass,spectrometer,during,stripping,indicates,can,hampered,Thus,high,Coulombic,efficiency,are,achieved,via,introducing,proposed,expected,facilitate,furthermore
AB值：
0.563809
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
