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典型文献
Enabling a stable and dendrite-suppressed Zn anode via facile surface roughness engineering
文献摘要:
The safety and cycle lifespan of zinc metal-based aqueous batteries are greatly restricted by zinc anode.The poor cycling performance of zinc metal anode is often considered to be impacted by the dendrite growth,surface passivation,zinc metal corrosion and hydrogen evolution reaction,while surface rough-ness is a matter that has often been ignored in past studies.Herein,a roughness gradient is constructed on the zinc anode surface by a simple grinding and pasting method.It has been found the modified zinc anodes with lower surface roughness exhibit the smaller zinc deposition overpotential and longer cycle life.Further,in situ optical microscopy photographs indicate that the zinc anode with an optimized rough-ness enables more uniform distribution of zinc precipitation and corrosion sites,which will facilitate a stable cycling performance of aqueous zinc ion batteries.The Zn anode dendrite-suppressing mechanism via surface roughness engineering was revealed through finite element computational simulation.These results emphasize the effectiveness of roughness engineering for tuning the surface physics of Zn anode and provide a facile strategy to develop better and safer aqueous zinc ion batteries.
文献关键词:
作者姓名:
Jinghao Li;Kehan Le;Wei Wei
作者机构:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;International School of Materials Science and Engineering,Wuhan University of Technology,Wuhan 430070,China;School of Materials Science and Engineering,Wuhan University of Technology,Wuhan 430070,China
引用格式:
[1]Jinghao Li;Kehan Le;Wei Wei-.Enabling a stable and dendrite-suppressed Zn anode via facile surface roughness engineering)[J].材料科学技术(英文版),2022(07):272-277
A类:
B类:
Enabling,stable,dendrite,suppressed,via,facile,surface,roughness,engineering,safety,cycle,lifespan,zinc,metal,aqueous,batteries,are,greatly,restricted,by,poor,cycling,performance,often,considered,impacted,growth,passivation,corrosion,hydrogen,evolution,reaction,while,matter,that,been,ignored,studies,Herein,gradient,constructed,simple,grinding,pasting,method,It,found,modified,anodes,lower,exhibit,smaller,deposition,overpotential,longer,Further,situ,optical,microscopy,photographs,indicate,optimized,enables,more,uniform,distribution,precipitation,sites,which,will,facilitate,suppressing,mechanism,was,revealed,through,finite,element,computational,simulation,These,results,emphasize,effectiveness,tuning,physics,provide,strategy,develop,better,safer
AB值:
0.526611
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