典型文献
Tuning crystal orientation and charge transport of quasi-2D perovskites via halogen-substituted benzylammonium for efficient solar cells
文献摘要:
Quasi-two-dimensional(quasi-2D)perovskites with high stability usually suffers from poor device effi-ciency.Chemical tuning of the spacer cations has been an effective strategy to achieve efficient and stable quasi-2D perovskite solar cells.Here,we demonstrate that 3-halogon-substituted benzylammonium iodide(3X-BAI,X=F,Cl,Br,I)can significantly affect the orientation of low-dimensional perovskites and charge transport from perovskite to hole extraction layer,as well as device performance.With 3Br-BAI,we achieve the highest device efficiency of 13.21%for quasi-2D perovskites with a nominal n=3 average composition.Our work provides a facile approach to regulate vertical crystal orientation and charge transport via tuning the molecular structure of organic spacer toward high performance quasi-2D perovskite solar cells.
文献关键词:
中图分类号:
作者姓名:
Guiqiang Cheng;Jian Wang;Rong Yang;Cheng Li;Hao Zhang;Nana Wang;Renzhi Li;Jianpu Wang;Wei Huang
作者机构:
Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM),Nanjing Tech University(NanjingTech),Nanjing 211816,Jiangsu,China;Frontiers Science Center for Flexible Electronics,Xi'an Institute of Flexible Electronics(IFE),Xi'an Institute of Biomedical Materials and Engineering,Northwestern Polytechnical University(NPU),Xi'an 710072,Shaanxi,China;School of Electronic Science and Engineering,Xiamen University,Xiamen 361005,Fujian,China
文献出处:
引用格式:
[1]Guiqiang Cheng;Jian Wang;Rong Yang;Cheng Li;Hao Zhang;Nana Wang;Renzhi Li;Jianpu Wang;Wei Huang-.Tuning crystal orientation and charge transport of quasi-2D perovskites via halogen-substituted benzylammonium for efficient solar cells)[J].能源化学,2022(03):205-209
A类:
benzylammonium,halogon,3Br
B类:
Tuning,crystal,orientation,charge,transport,quasi,2D,perovskites,via,halogen,substituted,efficient,solar,cells,Quasi,two,dimensional,stability,usually,suffers,from,poor,device,Chemical,tuning,spacer,cations,has,been,effective,strategy,achieve,stable,Here,demonstrate,that,iodide,3X,BAI,Cl,significantly,affect,low,hole,extraction,layer,well,performance,With,highest,efficiency,nominal,average,composition,Our,work,provides,facile,approach,regulate,vertical,molecular,structure,organic,toward
AB值:
0.499405
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