Solid-state thermoelectric energy conversion devices attract broad research interests because of their great promises in waste heat recycling,space power generation,deep water power generation,and temperature control,but the search for essential thermoelectric materials with high performance still remains a great challenge.As an emerging low cost,solution-processed thermoelectric material,inorganic metal halide perovskites CsPb(I1-xBrx)3 under mechanical deformation is systematically investigated using the first-principle calculations and the Boltzmann transport theory.It is demonstrated that halogen mixing and mechanical deformation are efficient methods to tailor electronic structures and charge transport properties in CsPb(I1-xBrx)3 synergistically.Halogen mixing leads to band splitting and anisotropic charge transport due to symmetry-breaking-induced intrinsic strains.Such band splitting reconstructs the band edge and can decrease the charge carrier effective mass,leading to excellent charge transport properties.Mechanical deformation can further push the orbital energies apart from each other in a more controllable manner,surpassing the impact from intrinsic strains.Both anisotropic charge transport properties and ZT values are sensitive to the direction and magnitude of strain,showing a wide range of variation from 20％to 400％(with a ZT value of up to 1.85)compared with unstrained cases.The power generation efficiency of the thermoelectric device can reach as high as approximately 12％using mixed halide perovskites under tailored mechanical deformation when the heat-source is at 500 K and the cold side is maintained at 300 K,surpassing the performance of many existing bulk thermoelectric materials.

Lifu YAN;Lingling ZHAO;Guiting YANG;Shichao LIU;Yang LIU;Shangchao LIN

National Engineering Research Center of Turbo-Generator Vibration,School of Energy and Environment,Southeast University,Nanjing 210096,China;State Key Laboratory of Space Power-Sources Technology,Shanghai Institute of Space Power-Sources,Shanghai 200245,China;Key Laboratory for Power Machinery and Engineering of the Ministry of Education,School of Mechanical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China

能源前沿

[1]Lifu YAN;Lingling ZHAO;Guiting YANG;Shichao LIU;Yang LIU;Shangchao LIN-.High performance solid-state thermoelectric energy conversion via inorganic metal halide perovskites under tailored mechanical deformation)[J].能源前沿,2022(04):581-594

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