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典型文献
High-performance supercapacitors based on free-standing SiC@PEDOT nanowires with robust cycling stability
文献摘要:
Conductive polymers as one of the candidate materials with pseudocapacitor behavior have inspired wide attentions,because of their high conductivity,flexibility,low cost and excellent processability.However,the intrinsically poor cycling stability induced by the volume change over the doping/dedoping redox process limits their practical applications.Herein,we report the exploration of electrodes with robust cycling capacity for supercapacitors(SCs),which are rationally designed by coating conductive poly(3,4-ethylenedioxythiophene)(PEDOT)around free-standing SiC nanowires using an all-dry oxida-tive chemical vaper deposition(oCVD)method.The as-constructed SiC@PEDOT nanowire architecture enables a specific capacitance of 26.53 mF/cm2 at 0.2 mA/cm2,which is~370%to that of SiC nanowire counterpart(7.04 mF/cm2).Moreover,their aqueous-based SCs exhibit robust cycling stability with 104%capacity retention after 10000 cycles,which is among the highest values achieved for PEDOT-based SCs.
文献关键词:
作者姓名:
Wenna Liu;Xiaoxiao Li;Weijun Li;Yumin Ye;Hong Wang;Peipei Su;Weiyou Yang;Ya Yang
作者机构:
Ningbo Key Laboratory of Specialty Polymers,School of Materials Science and Chemical Engineering,Ningbo University,Ningbo 315211,Zhejiang,China;Institute of Materials,Ningbo University of Technology,Ningbo 315016,Zhejiang,China;CAS Center for Excellence in Nanoscience,Beijing Key Laboratory of Micro-nano Energy and Sensor,Beijing Institute of Nanoenergy and Nanosystems,Chinese Academy of Sciences,Beijing 101400,China
文献出处:
引用格式:
[1]Wenna Liu;Xiaoxiao Li;Weijun Li;Yumin Ye;Hong Wang;Peipei Su;Weiyou Yang;Ya Yang-.High-performance supercapacitors based on free-standing SiC@PEDOT nanowires with robust cycling stability)[J].能源化学,2022(03):30-37
A类:
pseudocapacitor,dedoping,vaper,oCVD
B类:
High,performance,supercapacitors,free,standing,SiC,PEDOT,nanowires,robust,cycling,stability,Conductive,polymers,one,candidate,materials,behavior,have,inspired,wide,attentions,because,their,conductivity,flexibility,low,cost,excellent,processability,However,intrinsically,poor,induced,by,volume,change,redox,limits,practical,applications,Herein,report,exploration,electrodes,capacity,SCs,which,are,rationally,designed,coating,conductive,ethylenedioxythiophene,around,using,dry,oxida,chemical,deposition,method,constructed,architecture,enables,specific,capacitance,mF,mA,is,that,counterpart,Moreover,aqueous,exhibit,retention,after,cycles,among,highest,values,achieved
AB值:
0.565115
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