Flexible thermoelectric devices(F-TEDs)show great potentials to be applied in curved surface for power generation by harvesting low-grade energy from human body and other heat sources.However,their power generation efficiency is constrained by both unsatisfactory constituent materials perfor-mance and immature device design.Here,we used an optimal alignment of vertically-aligned poly(3,4-ethylenedioxythiophene)polystyrene sulfonate(PEDOT:PSS)arrays to assemble a 2.7×3.2 cm2 F-TEDs,exhibiting a maximum power output of 10.5 μW.Such a high performance can be ascribed to the out-standing power factor of 198 μW m-1 K-2 by the synergetic effect of both high charge mobility and optimal oxidation level and the optimized array alignment that maximizes the temperature difference utilization ratio across the TE legs.Particularly,optimized leg distance of 6 mm and leg length of 12 mm are determined to realize a high temperature difference utilization ratio of over 95％and a record-high output power density of 1.21 μW cm-2 under a temperature difference of 30 K.Further,reliable bending(1000 cycles)and stability(240 h)tests indicate the outstanding mechanical robustness and environmen-tal stability of the developed F-TEDs.This study indicates our reasonable device design concept and facile material treatment techniques secure high-performance F-TEDs,serving as a reference for other flexible energy harvesting devices with wide practical applications.

Shengduo Xu;Meng Li;Min Hong;Lei Yang;Qiang Sun;Shuai Sun;Wanyu Lyu;Matthew Dargusch;Jin Zou;Zhi-Gang Chen

School of Mechanical and Mining Engineering,The University of Queensland,Brisbane,Queensland,4072,Australia;Centre for Future Materials,University of Southern Queensland,Springfield Central,Queensland,4300,Australia;School of Materials Science&Engineering,Sichuan University,Chengdu 610064,China;Centre for Microscopy and Microanalysis,The University of Queensland,Brisbane,Queensland,4072,Australia;School of Chemistry and Physics,Queensland University of Technology,Brisbane,Queensland,4000,Australia

材料科学技术（英文版）

[1]Shengduo Xu;Meng Li;Min Hong;Lei Yang;Qiang Sun;Shuai Sun;Wanyu Lyu;Matthew Dargusch;Jin Zou;Zhi-Gang Chen-.Optimal array alignment to deliver high performance in flexible conducting polymer-based thermoelectric devices)[J].材料科学技术（英文版）,2022(29):252-259

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