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典型文献
N,S-codoped porous carbon nanosheets decorated with Fe3C nanoparticles as high-performance anode materials for lithium ion hybrid supercapacitors
文献摘要:
The practical applications of carbon anode for lithium-ion batteries(LIBs)are largely obstructed by their moderate rate capability and cyclic stability.Herein,we report a N,S-codoped porous carbon nanosheet(NSC)decorated with Fe3C nanoparticles(Fe3C/NSC)by a one-pot pyrolysis process.The high surface area and abundant defects of NSC can not only promote electrons and ions transfer,but also induce high pseudocapacitive contribution.More importantly,the synergistic catalysis effect of Fe-Nx and Fe3C can catalyze the reversible conversion of some solid electrolyte interface(SEI)components to offer excess capacity during cycling.As expected,the Fe3C-NSC anode delivers a discharge capacity of750 mAh·g-1 under a current density of 0.5 A·g-1 through 500 cycles and retains a dis-charge capacity of 366 mAh·g-1 at 4 A·g-1 after 1600 cycles,respectively.Most importantly,the lithium-ion capacitors based on Fe3C/NSC anode demonstrate a high energy density of 249.5 Wh·kg-1 at 560 W·kg-1.
文献关键词:
作者姓名:
Lin Gao;Lu-Lu Zhang;Xue-Lin Yang
作者机构:
College of Electrical Engineering&New Energy,Hubei Collaborative Innovation Center for Microgrid of New Energy,Three Gorges University,Yichang 443002,China
引用格式:
[1]Lin Gao;Lu-Lu Zhang;Xue-Lin Yang-.N,S-codoped porous carbon nanosheets decorated with Fe3C nanoparticles as high-performance anode materials for lithium ion hybrid supercapacitors)[J].稀有金属(英文版),2022(07):2517-2526
A类:
of750
B类:
codoped,porous,carbon,nanosheets,decorated,Fe3C,nanoparticles,high,performance,anode,materials,lithium,hybrid,supercapacitors,practical,applications,batteries,LIBs,largely,obstructed,by,their,moderate,capability,cyclic,stability,Herein,we,report,NSC,pot,pyrolysis,process,surface,area,abundant,defects,can,not,only,promote,electrons,transfer,also,induce,pseudocapacitive,contribution,More,importantly,synergistic,catalysis,effect,Nx,catalyze,reversible,conversion,some,solid,electrolyte,interface,SEI,components,offer,excess,capacity,during,cycling,expected,delivers,discharge,mAh,under,current,density,through,cycles,retains,after,respectively,Most,demonstrate,energy,Wh
AB值:
0.577652
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