典型文献
Synergistic Catalysis of Enzymes and Biomimetic MOFs:Immobilizing Cyt c on Two-dimensional MOFs to Enhance the Performance of Peroxidase
文献摘要：
Metal-organic frameworks(MOFs)have been widely regarded as promising carriers for enzyme immobilization owing to their advantages in improving loading and regulating interaction with enzymes.However,they are still suffering from the problems of slow mass transfer and compromising activity.In this paper,the active two-dimensional(2D)MOF of Cu-TCPP(Fe)[TCPP=tetrakis(4-carboxy-phenyl)porphyrin],which possesses the biomimetic architecture of peroxidase,was adopted to anchor cytochrome(Cyt c)for the enhancement of catalytic activity.The atomic/nanometer thickness and micrometer lateral dimension of 2D MOFs can ensure the full exposure of immobilized enzymes and a shorter diffusion distance for the reactant molecules.Besides,the active carrier can provide synergistic catalysis and activity compensation during the reaction.When tested in the decomposition reaction of H2O2,Cyt c/Cu-TCPP(Fe)exhibited nearly twice catalytic activity and an accelerated catalytic rate compared to free Cyt c.
文献关键词：
中图分类号：
作者姓名：
WANG Yitong;MENG Fanchen;SU Ruifa;SUN Changrui;HAN Qianqian;ZHANG Weina;ZHANG Suoying
作者机构：
Key Laboratory of Flexible Electronics(KLOFE),Institute of Advanced Materials(IAM),Nanjing Tech University,Nanjing 211816,P.R.China
文献出处：
引用格式：
[1]WANG Yitong;MENG Fanchen;SU Ruifa;SUN Changrui;HAN Qianqian;ZHANG Weina;ZHANG Suoying-.Synergistic Catalysis of Enzymes and Biomimetic MOFs:Immobilizing Cyt c on Two-dimensional MOFs to Enhance the Performance of Peroxidase)[J].高等学校化学研究（英文版）,2022(06):1356-1360
A类：
Immobilizing
B类：
Synergistic,Catalysis,Enzymes,Biomimetic,MOFs,Cyt,Two,dimensional,Enhance,Performance,Peroxidase,Metal,organic,frameworks,have,been,widely,regarded,carriers,immobilization,owing,their,advantages,improving,loading,regulating,interaction,enzymes,However,they,still,suffering,from,problems,slow,mass,transfer,compromising,activity,In,this,paper,active,two,2D,TCPP,tetrakis,carboxy,phenyl,porphyrin,which,possesses,biomimetic,architecture,peroxidase,was,adopted,anchor,cytochrome,enhancement,catalytic,atomic,nanometer,thickness,micrometer,lateral,can,ensure,full,exposure,immobilized,shorter,diffusion,distance,reactant,molecules,Besides,provide,synergistic,catalysis,compensation,during,reaction,When,tested,decomposition,H2O2,exhibited,nearly,twice,accelerated,compared,free
AB值：
0.675994
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