典型文献
Conductive Metal/Covalent Organic Frameworks for CO2 Electro-reduction
文献摘要:
Porous crystalline metal-organic frameworks(MOFs)and covalent organic frame-works(COFs)are promising platforms for electrocatalytic reduction of CO2(CO2RR)due to their large CO2 adsorption uptakes and periodically arranged single active sites.However,the appli-cations in CO2RR of the traditional MOFs and COFs are greatly limited by their low electron conductivity.In recent years,numerous types of MOFs and COFs with high intrinsic conductivity have been rationally designed and successfully constructed,and some of them have been ap-plied in CO2RR.In this review,the applications of conductive MOFs and COFs in CO2RR have been summarized.The conductive MOFs and COFs can be categorized according to the me-thods,in which the conductivity is enhanced,such as constructing fully π-conjugated backbones,donor-acceptor heterojunction,enhancing the π-π stacking interactions between organic moie-ties and/or the introduction of guest molecules.
文献关键词:
中图分类号:
作者姓名:
Chang-Pu Wan;Jun-Dong Yi;Rong Cao;Yuan-Biao Huang
作者机构:
State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;University of Chinese Academy of Sciences,Beijing 100049,China;School of Chemistry and Materials Science,Collaborative Innovation Center of Chemistry for Energy Materials(iChEM),University of Science and Technology of China,Hefei 230026,China;Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China,Fuzhou 350108,China
文献出处:
引用格式:
[1]Chang-Pu Wan;Jun-Dong Yi;Rong Cao;Yuan-Biao Huang-.Conductive Metal/Covalent Organic Frameworks for CO2 Electro-reduction)[J].结构化学,2022(05):1-14
A类:
moie
B类:
Conductive,Metal,Covalent,Organic,Frameworks,Electro,reduction,Porous,crystalline,metal,organic,frameworks,MOFs,covalent,COFs,are,promising,platforms,electrocatalytic,CO2RR,due,their,large,adsorption,uptakes,periodically,arranged,single,active,sites,However,traditional,greatly,limited,by,low,electron,conductivity,In,recent,years,numerous,types,high,intrinsic,have,been,rationally,designed,successfully,constructed,some,them,plied,this,review,applications,conductive,summarized,can,categorized,according,thods,which,enhanced,such,as,constructing,conjugated,backbones,donor,acceptor,heterojunction,enhancing,stacking,interactions,between,ties,introduction,guest,molecules
AB值:
0.622051
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