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典型文献
Ultrathin 2D Covalent Organic Framework Film Fabricated via Langmuir-Blodgett Method with a"Two-in-One"Type Monomer
文献摘要:
In recent years,covalent organic frameworks(COFs)are evolving as a novel kind of porous materials for catalysis and molecular separation,gas adsorption,etc.Various functional building blocks have been explored to tune the pore channels,including the pore size and structures.In this article,a new terphenyl(TP)based COF(TP-COF)was developed via a"two-in-one"strategy by using a symmetric A2B2 monomer,i.e.,4,4"-diamino-2',5'-diformyl-1,1'∶4',1"-terphenyl(DADFTP).The pore size of TP-COF was only 0.99 nm by shortening the arm length of the DADFTP monomer.Freestanding,continuous and ultrathin COF films could be facilely prepared at the air-liquid interface through the modified Langmuir-Blodgett(LB)method.TP-COF films exhibited high rejection of over 90%for dyes removal.
文献关键词:
作者姓名:
MENG Weijia;LI Yang;ZHAO Ziqiang;SONG Xiaoyu;LU Fanli;CHEN Long
作者机构:
Department of Chemistry,Tianjin Key Laboratory of Molecular Optoelec-tronic Science,Tianjin University,Tianjin 300072,P.R.China;State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,P.R.China
引用格式:
[1]MENG Weijia;LI Yang;ZHAO Ziqiang;SONG Xiaoyu;LU Fanli;CHEN Long-.Ultrathin 2D Covalent Organic Framework Film Fabricated via Langmuir-Blodgett Method with a"Two-in-One"Type Monomer)[J].高等学校化学研究(英文版),2022(02):440-445
A类:
diformyl,DADFTP
B类:
Ultrathin,2D,Covalent,Organic,Framework,Film,Fabricated,via,Langmuir,Blodgett,Method,Two,One,Type,Monomer,In,recent,years,covalent,organic,frameworks,COFs,evolving,novel,kind,porous,materials,catalysis,molecular,separation,gas,adsorption,etc,Various,functional,building,blocks,have,been,explored,tune,pore,channels,including,size,structures,this,article,new,terphenyl,was,developed,two,one,strategy,by,using,symmetric,A2B2,monomer,diamino,only,shortening,arm,length,Freestanding,continuous,ultrathin,films,could,facilely,prepared,air,liquid,interface,through,modified,LB,method,exhibited,high,rejection,over,dyes,removal
AB值:
0.684701
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