典型文献
Rare-earth,nitrogen-rich,oxygen heterocyclic supramolecular compounds (Nd,Sm,and Eu):Synthesis,structure,and catalysis for ammonium perchlorate
文献摘要：
Three novel rare-earth,nitrogen-rich and oxygen heterocyclic supramolecular complexes,namely[Nd(BTF)2(H2O)5]n,[Sm(BTF)2(H2O)5]n,and[Eu(BTF)2(H2O)5]n,were synthesized.A single crystal was ob-tained by the solvent evaporation method,and the structure and coordination mode of metal complexes were determined by single crystal X-ray diffraction.Results show that the supramolecular complexes contain many hydrogen bonds and thus have good thermal stability (Tdec ＞ 540 K).The thermal decomposition of ammonium perchlorate (AP) catalyzed by the complexes was investigated by differ-ential thermal analysis,which reveals a pre-eminent catalytic effect on AP.The high temperature decomposition peak of AP can be advanced by nearly 90 K at the amount of added complexes of 10 wt％,and the activation energy of AP descent range is from 70 to 150 kJ/mol.The other properties were fully characterized through elemental analysis and Fourier transform infrared spectroscopy.
文献关键词：
中图分类号：
作者姓名：
Wenjia Hao;Tao Huang;Bo Jin;Jinhao Zhang;Juan Shen;Rufang Peng
作者机构：
State Key Laboratory of Environment-friendly Energy Materials,School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,China
文献出处：
引用格式：
[1]Wenjia Hao;Tao Huang;Bo Jin;Jinhao Zhang;Juan Shen;Rufang Peng-.Rare-earth,nitrogen-rich,oxygen heterocyclic supramolecular compounds (Nd,Sm,and Eu):Synthesis,structure,and catalysis for ammonium perchlorate)[J].稀土学报（英文版）,2022(03):428-433
A类：
BTF,Tdec
B类：
Rare,earth,nitrogen,rich,oxygen,heterocyclic,supramolecular,compounds,Nd,Sm,Eu,Synthesis,structure,catalysis,ammonium,perchlorate,Three,novel,complexes,namely,H2O,were,synthesized,single,crystal,was,ob,tained,by,solvent,evaporation,method,coordination,mode,metal,determined,ray,diffraction,Results,show,that,contain,many,hydrogen,bonds,thus,have,good,thermal,stability,decomposition,AP,catalyzed,investigated,differ,ential,analysis,which,reveals,pre,eminent,catalytic,effect,high,temperature,peak,can,be,advanced,nearly,amount,added,wt,activation,energy,descent,range,from,kJ,other,properties,fully,characterized,through,elemental,Fourier,transform,infrared,spectroscopy
AB值：
0.608747
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