典型文献
Recent Advances on Confining Noble Metal Nanoparticles Inside Metal-Organic Frameworks for Hydrogenation Reactions
文献摘要:
Hydrogenation reaction is one of the pillars of the chemical industry for the synthesis of drugs and fine chemicals.To achieve high catalytic performance,it is still highly desirable for constructing novel supported metal catalysts.Different from conventional supports like metal oxides,zeolites and carbon materials,metal-organic frameworks(MOFs)as the emerging porous materials have exhibited great potential to host metal nanoparticles(NPs)for achieving hydrogenation reactions with high catalytic efficiency,due to their unique porous structures.Recently,many progresses have been made,and thus,it is necessary to summarize the recent progresses on confining metal NPs inside MOFs for hydrogenation reactions.In this review,we first introduced the general synthesis methods for confining noble metal NPs inside MOFs.Then,the applications of noble metal NPs/MOFs catalysts in hydrogenation reactions were summarized,and the synergistic catalytic performances among noble metal NPs,metal nodes,functional groups,and pore channels in MOFs were illustrated.Subsequently,the hydrogen spillover effect involved in the hydrogenation reactions was discussed.Finally,we provide an outlook on the future research directions and challenges of confining noble metal NPs inside MOFs for hydrogenation reactions.
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作者姓名:
LIN Tian;WANG Haowu;CUI Chengqian;LIU Wei;LI Guodong
作者机构:
School of Chemical Science,University of Chinese Academy of Sciences,Beijing 100190,P.R.China;Chinese Academy of Sciences(CAS)Key Laboratory of Nanosystem and Hierarchical Fabrication,CAS Center for Excellence in Nanoscience,National Center for Nanoscience and Technology,Beijing 100190,P.R.China;School of Nanoscience and Technology,University of Chinese Academy of Sciences,Beijing 100049,P.R.China
文献出处:
引用格式:
[1]LIN Tian;WANG Haowu;CUI Chengqian;LIU Wei;LI Guodong-.Recent Advances on Confining Noble Metal Nanoparticles Inside Metal-Organic Frameworks for Hydrogenation Reactions)[J].高等学校化学研究(英文版),2022(06):1309-1323
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Advances,Confining,Noble,Metal,Nanoparticles,Inside,Organic,Frameworks,Hydrogenation,Reactions,one,pillars,industry,synthesis,drugs,fine,chemicals,To,achieve,catalytic,still,highly,desirable,constructing,novel,supported,metal,catalysts,Different,from,conventional,supports,like,oxides,zeolites,carbon,materials,organic,frameworks,MOFs,emerging,porous,have,exhibited,great,potential,host,nanoparticles,NPs,achieving,hydrogenation,reactions,efficiency,due,their,unique,structures,Recently,many,progresses,been,made,thus,necessary,recent,confining,inside,this,review,first,introduced,general,methods,noble,Then,applications,were,summarized,synergistic,performances,among,nodes,functional,groups,pore,channels,illustrated,Subsequently,spillover,effect,involved,was,discussed,Finally,provide,outlook,future,research,directions,challenges
AB值:
0.558411
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