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典型文献
Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR)
文献摘要:
Exploring novel materials deriving from earth resources to substitute for platinum(Pt)electrocatalyst to promote oxygen reduction reaction(ORR)of fuel cell cathode is very important.Herein,we have exploited two crystallographic thiophene-sulfur covalent organic frameworks(COFs),termed JUC-607 and JUC-608,as electrocatalysts that exhibited good ORR performances.These thiophene-sulfur COFs exhibited high stability,and their functional groups acting as active centers in the ORR can be precisely determined.Notably,due to a larger aperture for mass transfer and electrons transport,JUC-608 displayed a growing electrochemical performance,leading to a better ORR activity.Thus,this study will provide a new strategy for designing heteroatom-based COF materials for high-performance electrochemical catalysis.
文献关键词:
作者姓名:
CHANG Shunkai;LI Cuiyan;LI Hui;ZHU Liangkui;FANG Qianrong
作者机构:
State Key Laboratory of Inorganic Synthesis&Preparative Chemistry,Jilin University,Changchun 130012,P.R.China
引用格式:
[1]CHANG Shunkai;LI Cuiyan;LI Hui;ZHU Liangkui;FANG Qianrong-.Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR))[J].高等学校化学研究(英文版),2022(02):396-401
A类:
Thiophene
B类:
Stable,sulfur,Covalent,Organic,Frameworks,Oxygen,Reduction,Reaction,ORR,Exploring,novel,materials,deriving,from,earth,resources,substitute,platinum,Pt,promote,oxygen,reduction,reaction,fuel,cell,cathode,very,important,Herein,we,have,exploited,two,crystallographic,thiophene,covalent,organic,frameworks,COFs,termed,JUC,electrocatalysts,that,exhibited,good,performances,These,high,stability,their,functional,groups,acting,active,centers,can,precisely,determined,Notably,due,larger,aperture,mass,transfer,electrons,transport,displayed,growing,electrochemical,leading,better,activity,Thus,this,study,will,provide,new,strategy,designing,heteroatom,catalysis
AB值:
0.716449
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