典型文献
Oxidative Cross-Coupling Reactions between Two Nucleophiles
文献摘要：
Oxidative cross-coupling reactions between two nucleophiles have become one of the most important tools to construct chemical bonds in organic synthesis methodology.Directly using hydrocarbons to synthesize valuable chemicals is an ideal and economical process because hydrocarbons are cheap,abundant and readily available.The account covered a brief introduction about our efforts on the development of oxidative cross-coupling reactions.We discovered this reaction model by the cross-coupling of two organometallic reagents.Related mechanisms were revealed by the char-acterization of reaction intermediates and the study of reaction kinetics through operando spectroscopy,such as in-situ IR (infrared),EPR (electron paramagnetic resonance),Raman and XAS (X-ray absorption) spectroscopy.Representative applications,such as oxidative cross-coupling reactions with H2 evolution,exhibited their high atom economy and step economy.
文献关键词：
中图分类号：
作者姓名：
Lijun Lu;Hao Li;Aiwen Lei
作者机构：
Institute for Advanced Studies (IAS),College of Chemistry and Molecular Sciences,Wuhan University,Wuhan,Hubei 430072,China
文献出处：
引用格式：
[1]Lijun Lu;Hao Li;Aiwen Lei-.Oxidative Cross-Coupling Reactions between Two Nucleophiles)[J].中国化学（英文版）,2022(02):256-266
A类：
Nucleophiles
B类：
Oxidative,Cross,Coupling,Reactions,between,Two,cross,coupling,reactions,two,nucleophiles,have,become,one,most,important,tools,construct,bonds,organic,synthesis,methodology,Directly,using,hydrocarbons,synthesize,valuable,chemicals,ideal,economical,process,because,cheap,abundant,readily,available,account,brief,introduction,about,our,efforts,development,oxidative,We,discovered,this,model,by,organometallic,reagents,Related,mechanisms,were,revealed,char,acterization,intermediates,study,kinetics,through,operando,spectroscopy,such,as,situ,infrared,EPR,electron,paramagnetic,resonance,Raman,XAS,ray,absorption,Representative,applications,H2,evolution,exhibited,their,high,atom,economy,step
AB值：
0.712121
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