典型文献
In situ structural reconstruction of NiMo alloy as a versatile organic oxidation electrode for boosting hydrogen production
文献摘要:
Substitution of the electrocatalytic oxygen evolution by value-added organic synthesis is an effective and promis-ing strategy to improve the efficiency of hydrogen evolu-tion.Here,the NiMo nanorod array electrode is fabricated as the multifunctional electrode for diverse electrocatalytic organic oxidation reactions to generate carboxylic acids,nitriles,and dihydroisoquinolines(DHIQs)with high yields and high selectivity.NiⅢ species are confirmed as domi-nant intermediates by in situ Raman spectroscopy to pro-mote the organic oxidation.And the leaching Mo component helps the surface reconstruction to expose more Nim active sites,thus enhancing the catalytic performance.Additionally,the bifunctional NiMo electrodes can be assembled into a two-electrode electrolyzer for boosting hydrogen production by coupling with the furfural oxy-genation at a smaller voltage than that of overall water splitting.
文献关键词:
中图分类号:
作者姓名:
Qi Liu;Meng-Yang Li;Yan-Mei Shi;Cui-Bo Liu;Yi-Fu Yu;Bin Zhang
作者机构:
Department of Chemistry,School of Science,Institute of Molecular Plus,Tianjin University,Tianjin 300072,China;Tianjin Key Laboratory of Molecular Optoelectronic Sciences,Tianjin University,Tianjin 300072,China
文献出处:
引用格式:
[1]Qi Liu;Meng-Yang Li;Yan-Mei Shi;Cui-Bo Liu;Yi-Fu Yu;Bin Zhang-.In situ structural reconstruction of NiMo alloy as a versatile organic oxidation electrode for boosting hydrogen production)[J].稀有金属(英文版),2022(03):836-843
A类:
nitriles,dihydroisoquinolines,DHIQs
B类:
In,situ,structural,reconstruction,NiMo,alloy,versatile,organic,oxidation,boosting,hydrogen,production,Substitution,electrocatalytic,oxygen,evolution,by,value,added,synthesis,effective,promis,strategy,improve,efficiency,Here,nanorod,array,fabricated,multifunctional,diverse,reactions,generate,carboxylic,acids,high,yields,selectivity,species,are,confirmed,domi,nant,intermediates,Raman,spectroscopy,mote,And,leaching,component,helps,surface,expose,more,Nim,active,sites,thus,enhancing,performance,Additionally,bifunctional,electrodes,can,be,assembled,into,two,electrolyzer,coupling,furfural,genation,smaller,voltage,than,that,overall,water,splitting
AB值:
0.612109
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