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典型文献
Biodegradable Foaming Material of Poly(butylene adipate-co-terephthalate) (PBAT)/Poly(propylene carbonate) (PPC)
文献摘要:
A biodegradable blend foaming material of poly(butylene adipate-co-terephthalate) (PBAT)/poly(propylene carbonate) (PPC) was successfully prepared by chemical foaming agent and screw extrusion method.First,PBAT was modified by bis(tert-butyl dioxy isopropyl)benzene (BIBP) for chain extension,and then the extended PBAT (E-PBAT) was foamed with PPC using a twin (single) screw extruder.By analyzing the properties of the blends,we found that Young's modulus increased from 58.8 MPa of E-PBAT to 244.7 MPa of E-PBAT/PPC 50/50.The viscosity of the polymer has a critical influence on the formation of cells.Compared with neat PBAT (N-PBAT),the viscosity of E-PBAT increased by 3396 Pa.s and E-PBAT/PPC 50/50 increased by 8836 Pa.s.Meanwhile,the dynamic mechanical analysis (DMA) results showed that the storage modulus(E') at room temperature increased from 538 MPa to 1650 MPa.The various phase morphologies ("sea-island","quasi-co-continuous" and "co-continuous") and crystallinity of the blends affected the spread velocity of gas and further affected the foaming morphology in E-PBAT/PPC foam.Therefore,through the analysis of phase morphology and foaming mechanism,we concluded that the E-PBAT/PPC 70/30 component has both excellent strength and the best foaming performance.
文献关键词:
作者姓名:
Han-Lin Tian;Ze-Peng Wang;Shi-Ling Jia;Hong-Wei Pan;Li-Jing Han;Jun-Jia Bian;Ying Li;Hui-Li Yang;Hui-Liang Zhang
作者机构:
Changchun University of Technology,School of Chemical Engineering,Changchun 130012,China;Key Laboratory of Polymer Ecomaterials,Chinese Academy of Sciences,Changchun Institute of Applied Chemistry,Changchun 130022,China;Jilin COFCO Biochemistry Packaging Co.,Ltd.,Liaoyuan 136300,China
引用格式:
[1]Han-Lin Tian;Ze-Peng Wang;Shi-Ling Jia;Hong-Wei Pan;Li-Jing Han;Jun-Jia Bian;Ying Li;Hui-Li Yang;Hui-Liang Zhang-.Biodegradable Foaming Material of Poly(butylene adipate-co-terephthalate) (PBAT)/Poly(propylene carbonate) (PPC))[J].高分子科学(英文版),2022(02):208-219
A类:
dioxy,extruder
B类:
Biodegradable,Foaming,Material,Poly,butylene,adipate,terephthalate,PBAT,propylene,carbonate,PPC,biodegradable,foaming,material,was,successfully,prepared,by,chemical,agent,screw,extrusion,method,First,modified,bis,tert,isopropyl,benzene,BIBP,chain,extension,then,extended,foamed,using,twin,single,By,analyzing,properties,blends,found,that,Young,modulus,increased,from,viscosity,polymer,critical,influence,formation,cells,Compared,neat,Meanwhile,dynamic,mechanical,analysis,DMA,results,showed,storage,room,temperature,various,phase,morphologies,sea,island,quasi,continuous,crystallinity,affected,spread,velocity,gas,further,morphology,Therefore,through,mechanism,concluded,component,both,excellent,strength,best,performance
AB值:
0.502958
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