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典型文献
An Effective Green Porous Structural Adhesive for Thermal Insulating,Flame-Retardant,and Smoke-Suppressant Expandable Polystyrene Foam
文献摘要:
To develop an efficient way to overcome the contradiction among flame retardancy,smoke suppression,and thermal insulation in expanded polystyrene(EPS)foams,which are widely used insulation materials in buildings,a novel"green"porous bio-based flame-retardant starch(FRS)coating was designed from starch modified with phytic acid(PA)that simultaneously acts as both a flame retardant and an adhesive.This porous FRS coating has open pores,which,in combination with the closed cells formed by EPS beads,create a hierarchically porous structure in FRS-EPS that results in superior thermal insulation with a lower thermal conductivity of 27.0 mW-(m-K)-1.The resultant FRS-EPS foam showed extremely low heat-release rates and smoke-production release,indicating excellent fire retardancy and smoke suppres-sion.The specific optical density was as low as 121,which was 80.6%lower than that of neat EPS,at 624.The FRS-EPS also exhibited self-extinguishing behavior in vertical burning tests and had a high limiting oxygen index(LOI)value of 35.5%.More interestingly,after being burnt with an alcohol lamp for 30 min,the top side temperature of the FRS-EPS remained at only 140℃with ignition,thereby exhibiting excel-lent fire resistance.Mechanism analysis confirmed the intumescent action of FRS,which forms a compact phosphorus-rich hybrid barrier,and the phosphorus-containing compounds that formed in the gas phase contributed to the excellent flame retardancy and smoke suppression of FRS-EPS.This novel porous biomass-based FRS system provides a promising strategy for fabricating polymer foams with excellent flame retardancy,smoke suppression,and thermal insulation.
文献关键词:
作者姓名:
Meng-En Li;Hai-Bo Zhao;Jin-Bo Cheng;Ting Wang;Teng Fu;Ai-Ning Zhang;Yu-Zhong Wang
作者机构:
The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE)&r State Key Laboratory of Polymer Materials Engineering Er National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan),College of Chemistry,Sichuan University,Chengdu 610064,China
文献出处:
引用格式:
[1]Meng-En Li;Hai-Bo Zhao;Jin-Bo Cheng;Ting Wang;Teng Fu;Ai-Ning Zhang;Yu-Zhong Wang-.An Effective Green Porous Structural Adhesive for Thermal Insulating,Flame-Retardant,and Smoke-Suppressant Expandable Polystyrene Foam)[J].工程(英文),2022(10):151-160
A类:
Suppressant,Expandable,intumescent
B类:
An,Effective,Green,Porous,Structural,Adhesive,Thermal,Insulating,Flame,Retardant,Smoke,Polystyrene,Foam,To,develop,efficient,way,overcome,contradiction,among,flame,retardancy,smoke,suppression,thermal,insulation,expanded,polystyrene,EPS,foams,which,are,widely,used,materials,buildings,novel,green,porous,retardant,starch,FRS,coating,was,designed,from,modified,phytic,acid,PA,that,simultaneously,acts,both,adhesive,This,open,pores,combination,closed,cells,formed,beads,create,hierarchically,structure,results,superior,lower,conductivity,mW,resultant,showed,extremely,heat,release,rates,production,indicating,excellent,fire,specific,optical,density,than,neat,also,exhibited,self,extinguishing,behavior,vertical,burning,tests,had,high,limiting,oxygen,LOI,value,More,interestingly,after,being,burnt,alcohol,lamp,top,side,temperature,remained,only,ignition,thereby,exhibiting,resistance,Mechanism,analysis,confirmed,action,forms,compact,phosphorus,rich,hybrid,barrier,containing,compounds,gas,phase,contributed,biomass,system,provides,promising,strategy,fabricating,polymer
AB值:
0.565556
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