首站-论文投稿智能助手
典型文献
Template-mediated strategy to regulate hierarchically nitrogen-sulfur co-doped porous carbon as superior anode material for lithium capacity
文献摘要:
Considering its rapid lithiation/delithiation process and robust capacitive energy storage,hierarchical porous carbon is regarded as a promising candidate for lithium-ion batteries(LIBs).However,it remains a great challenge to construct a porous structure and prevent structure stacking for carbon-based materials.Herein,a template-mediated approach is developed to synthesize hierarchical nitrogen-sulfur co-doped porous carbon(NSPC)using low-cost asphalt precursors.The strategy for synthesis uses g-C3N4 and NaHCO3 as gaseous templates and NaCl as a solid template,which causes the formation of hierarchical porous carbon with a high specific surface area.The resultant porous structure and nitrogen-doping process can prevent the aggregation of nanosheets,maintain the structural stability upon cycling,and achieve rate-capable lithium storage.Serving as a LIBs anode,reversible specific capacities of the NSPC24 electrode reach 788 and 280 mAh·g-1 at 0.1 and 1 A·g-1,respectively.Furthermore,its specific capacity remains at 830 mAh·g-1 after 115 cycles at 0.1 Ag-1.Even after 500 cycles,high specific capacities of 727 mAh·g-1 at 0.5 A·g-1 and 624 mAh·g-1 at 1 A·g-1 are achieved,demonstrating excellent cycling performance.The gas-solid bifunctional template-mediated approach can guide the design of porous materials very well,meanwhile realizing the high value-added utilization of asphalt.
文献关键词:
作者姓名:
Yun LI;Wang YANG;Hanlin LIU;Zhiqiang TU;Sai CHE;Bo JIANG;Chong XU;Guang MA;Guoyong HUANG;Yongfeng Li
作者机构:
State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China;SINOPEC Research Institute of Petroleum Processing,Beijing 100083,China
文献出处:
引用格式:
[1]Yun LI;Wang YANG;Hanlin LIU;Zhiqiang TU;Sai CHE;Bo JIANG;Chong XU;Guang MA;Guoyong HUANG;Yongfeng Li-.Template-mediated strategy to regulate hierarchically nitrogen-sulfur co-doped porous carbon as superior anode material for lithium capacity)[J].材料学前沿,2022(01):157-170
A类:
NSPC24
B类:
Template,mediated,strategy,regulate,hierarchically,nitrogen,sulfur,doped,porous,carbon,superior,anode,lithium,capacity,Considering,its,rapid,delithiation,process,robust,capacitive,energy,storage,regarded,promising,candidate,batteries,LIBs,However,remains,great,challenge,construct,structure,prevent,stacking,materials,Herein,approach,developed,synthesize,using,low,cost,asphalt,precursors,synthesis,C3N4,NaHCO3,gaseous,templates,NaCl,solid,which,causes,formation,high,specific,surface,area,resultant,doping,aggregation,nanosheets,maintain,structural,stability,upon,cycling,capable,Serving,reversible,capacities,electrode,reach,mAh,respectively,Furthermore,after,cycles,Ag,Even,achieved,demonstrating,excellent,performance,bifunctional,guide,design,very,well,meanwhile,realizing,value,added,utilization
AB值:
0.52299
相似文献
Boosting the potassium-ion storage performance enabled by engineering of hierarchical MoSSe nanosheets modified with carbon on porous carbon sphere
Mengting Cai;Hehe Zhang;Yinggan Zhang;Bensheng Xiao;Lei Wang;Miao Li;Ying Wu;Baisheng Sa;Honggang Liao;Li Zhang;Shuangqiang Chen;Dong-Liang Peng;Ming-Sheng Wang;Qiaobao Zhang-Department of Materials Science and Engineering,College of Materials,Xiamen University,Xiamen 361005,China;Department of Chemical Engineering,School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China;School of Materials and Energy,Lanzhou University,Lanzhou 730000,China;Key Laboratory of Eco-materials Advanced Technology,College of Materials Science and Engineering,Fuzhou University,Fuzhou 350108,China;College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China;Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(IKKEM),Xiamen 361005,China
机标中图分类号,由域田数据科技根据网络公开资料自动分析生成,仅供学习研究参考。