典型文献
Site occupation and energy transfer in full color emitting phosphor Ba2Ca(BO3)2∶Ce3+(K+),Eu2,Mn2+
文献摘要:
White light-emitting diodes(WLEDs)fabricated by single-phase full color emitting phosphor are an emerging solution for health lighting.The crystallographic site occupation of activators in a proper host lattice is crucial for sophisticated design of such phosphor.Here,we report a high quality white light-emitting phosphor Ba2Ca(BO3)2∶Ce3+(K+),Eu2+,Mn2+with spectral distribution covering whole visible region.Blue light emission originates from Ce3+ions occupying preferentially Ba2+site by controlling synthesis conditions.Green and red lights are obtained from Eu2+occupying Ba2+(and Ca2+)site and Mn2+occupying Ca2+site,respectively.In this triple-doped phosphor,strong red emission with a low concentration of Mn2+is realized by the efficient energy transfer from Ce3+and Eu2+to Mn2+.Furthermore,high quality white light is accomplished by properly tuning the relative doping amount of Ce3+(K+)/Eu2+/Mn2+based on efficient simultaneous energy transfer.The results indicate that Ba2Ca(BO3)2∶Ce3+(K+),Eu2+,Mn2+is a promising white light-emitting phosphor in WLEDs application.
文献关键词:
中图分类号:
作者姓名:
Qingsong Hu;Zaifa Pan;Guijie Liang
作者机构:
Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices,Hubei University of Arts and Science,Xiangyang 441053,China;College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,China
文献出处:
引用格式:
[1]Qingsong Hu;Zaifa Pan;Guijie Liang-.Site occupation and energy transfer in full color emitting phosphor Ba2Ca(BO3)2∶Ce3+(K+),Eu2,Mn2+)[J].稀土学报(英文版),2022(11):1691-1698
A类:
Ba2Ca,Mn2+with,Ce3+ions,Ba2+site,Eu2+occupying,Mn2+occupying,Ca2+site,Mn2+is,Eu2+to,Mn2+based
B类:
Site,occupation,energy,transfer,full,color,emitting,phosphor,BO3,K+,White,diodes,WLEDs,fabricated,by,single,phase,are,emerging,solution,health,lighting,crystallographic,activators,host,lattice,crucial,sophisticated,design,such,Here,we,report,high,quality,white,spectral,distribution,covering,whole,visible,region,Blue,emission,originates,from,preferentially,controlling,synthesis,conditions,Green,red,lights,obtained,respectively,In,this,triple,doped,strong,low,concentration,realized,efficient,Ce3+and,Furthermore,accomplished,properly,tuning,relative,doping,amount,simultaneous,results,indicate,that,promising,application
AB值:
0.445588
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