典型文献
Boosting Hydrogen Evolution and Oxygen Reduction Performances of Pd/C upon Surface Phosphorization
文献摘要：
Simultaneous heterostructure and composition engineering is an effective route to construct electrocatalyst of high performance. Conjugated microporous polymer ( CMP) is a new emerging platform material with designable porosity and functionality. Here, a facile CMP-guest chemistry method was presented to prepare PdP2@Pd/C heterostructure with bifunctional electrocatalytic activity. The formation of heterostructure relies on a CMP precursor consisting of nitrogen groups that allow binding Pd species and introducing phosphorus inclusion. The Pd-bound CMP precursor formed in-situ could be directly converted into nitrogen- and phosphide-doped porous carbon ( NPC) during pyrolysis, while P diffused to the Pd/C interface results in shallow phosphorization. The as-prepared NPC consisting of PdP2@ Pd/C ( Pd content 4 wt％) heterostructure demonstrated significantly enhanced electrocatalytic performances including a promising HER activity ( 58mV @ 10 mA/cm2 ) , and an ORR activity approaching commercial 20 wt％Pd/C together with excellent long-term stability. Our work illustrates the intriguing power of CMP-guest potential in heterostructure engineering.
文献关键词：
中图分类号：
作者姓名：
Tongtong Zhu;Haige Wang;Xiaopeng Li;Yaozu Liao;Meifang Zhu
作者机构：
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China
文献出处：
引用格式：
[1]Tongtong Zhu;Haige Wang;Xiaopeng Li;Yaozu Liao;Meifang Zhu-.Boosting Hydrogen Evolution and Oxygen Reduction Performances of Pd/C upon Surface Phosphorization)[J].哈尔滨工业大学学报（英文版）,2022(06):74-88
A类：
Phosphorization,PdP2
B类：
Boosting,Hydrogen,Evolution,Oxygen,Reduction,Performances,upon,Surface,Simultaneous,heterostructure,composition,engineering,effective,route,construct,electrocatalyst,high,Conjugated,microporous,polymer,CMP,new,emerging,platform,material,designable,porosity,functionality,Here,facile,guest,chemistry,method,was,presented,bifunctional,electrocatalytic,activity,formation,relies,precursor,consisting,nitrogen,groups,that,binding,species,introducing,phosphorus,inclusion,bound,formed,situ,could,be,directly,converted,into,phosphide,doped,carbon,NPC,during,pyrolysis,while,diffused,interface,results,shallow,phosphorization,prepared,content,wt,demonstrated,significantly,enhanced,performances,including,promising,HER,58mV,mA,ORR,approaching,commercial,together,excellent,long,term,stability,Our,work,illustrates,intriguing,power,potential
AB值：
0.648214
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