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典型文献
Improved methanol synthesis performance of Cu/ZnO/Al203 catalyst by controlling its precursor structure
文献摘要:
Methanol,a versatile chemical,fuel additive and potential H2 carrier,has attracted great attention.Despite of the wide industrialization,improvement of Cu-based methanol-synthesis catalysts is highly anticipated.Accordingly,a series of Cu/ZnO/Al2O3 with designed precursor structures were prepared,and its structure-function relationship was investigated to make progress on this area.Results showed the catalyst derived from highly zinc-substituted malachite demonstrated the best catalytic performance in this work.It was found that the well-behaved catalyst possessed relatively high Cu specific surface area and exposed Cu concentration,and the well Cu/ZnO synergy.CuZn alloy was found by In-situ XRD tests,and its effect on the catalyst's thermostability was discussed.Fractional precipitation,which facilitated the Cu2+sub-stitution by Zn2+in malachite lattice,could be an efficient preparation method of the Cu/ZnO/Al2O3 catalyst.
文献关键词:
作者姓名:
Fan Zhang;Xiaoying Xu;Zhengpu Qiu;Bo Feng;Yuan Liu;Aihua Xing;Maohong Fan
作者机构:
National Institute of Clean-and-Low-Carbon Energy,Beijing,102211,China;Departments of Chemical and Petroleum Engineering,University of Wyoming,Laramie,WY 82071,USA
引用格式:
[1]Fan Zhang;Xiaoying Xu;Zhengpu Qiu;Bo Feng;Yuan Liu;Aihua Xing;Maohong Fan-.Improved methanol synthesis performance of Cu/ZnO/Al203 catalyst by controlling its precursor structure)[J].绿色能源与环境(英文),2022(04):772-781
A类:
Cu2+sub
B类:
Improved,methanol,synthesis,performance,ZnO,Al203,by,controlling,its,precursor,Methanol,versatile,chemical,fuel,additive,potential,H2,carrier,has,attracted,great,attention,Despite,wide,industrialization,improvement,catalysts,highly,anticipated,Accordingly,series,Al2O3,designed,structures,were,prepared,function,relationship,was,investigated,make,progress,this,area,Results,showed,derived,from,zinc,substituted,malachite,demonstrated,best,catalytic,work,It,found,that,well,behaved,possessed,relatively,specific,surface,exposed,concentration,synergy,CuZn,alloy,In,situ,tests,effect,thermostability,discussed,Fractional,precipitation,which,facilitated,stitution,Zn2+in,lattice,could,efficient,preparation,method
AB值:
0.651366
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