典型文献
Dimethoxymethane production via CO2 hydrogenation in methanol over novel Ru based hierarchical BEA
文献摘要：
Dimethoxymethane(DMM),a diesel blend fuel,is being researched with high interest recently due to its unique fuel properties.It is commercially produced via a two step-process of methanol oxidation to make formaldehyde,followed by its condensation with methanol.This study presents a one-pot method of DMM synthesis from methanol mediated carbon dioxide hydrogenation over novel heterogeneous cata-lysts.The effect of catalyst pore structure was investigated by synthesizing 3 wt％Ru over novel hierar-chical zeolite beta(HBEASX)and comparing against Ru doped commercial zeolite beta(CBEA)and desilicated hierarchical zeolite beta(HBZDS).The results showed that 3％Ru/HBEASX provided the best activity for DMM production due to its large average pore size.It also showed the decisive role of SiO2/Al2O3 molar ratio,with SiO2/Al2O3=75 providing the highest DMM yield of 13.2 mmol/gcat.LMeOH with ca.100％selectivity.The activity of 3％Ru/HBEAS3 after 5 recycle steps demonstrated the reusability of this catalyst.
文献关键词：
中图分类号：
作者姓名：
Waqar Ahmad;Fan Liang Chan;Abhijit Shrotri;Yayati Naresh Palai;Huanting Wang;Akshat Tanksale
作者机构：
Department of Chemical Engineering,Monash University,Clayton 3800,Australia;Institute for Catalysis,Hokkaido University,Sapporo 001-0021,Japan
文献出处：
引用格式：
[1]Waqar Ahmad;Fan Liang Chan;Abhijit Shrotri;Yayati Naresh Palai;Huanting Wang;Akshat Tanksale-.Dimethoxymethane production via CO2 hydrogenation in methanol over novel Ru based hierarchical BEA)[J].能源化学,2022(03):181-189
A类：
Dimethoxymethane,HBEASX,CBEA,desilicated,HBZDS,LMeOH,HBEAS3
B类：
production,via,hydrogenation,methanol,over,novel,Ru,hierarchical,DMM,diesel,blend,fuel,being,researched,interest,recently,due,its,unique,properties,It,commercially,produced,two,process,oxidation,make,formaldehyde,followed,by,condensation,This,study,presents,one,pot,method,synthesis,from,mediated,carbon,dioxide,heterogeneous,lysts,effect,catalyst,pore,structure,was,investigated,synthesizing,wt,zeolite,beta,comparing,against,doped,results,showed,that,provided,best,activity,large,average,size,also,decisive,role,SiO2,Al2O3,molar,ratio,providing,highest,yield,gcat,selectivity,after,recycle,steps,demonstrated,reusability,this
AB值：
0.515405
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
