典型文献
Hierarchical assembly of uranyl metallacycles involving macrocyclic hosts
文献摘要：
Actinide metallacycles are an emerging class of functional coordination assemblies,but multi-level as-sembly from metallacycle units toward hierarchical supramolecular structures are still rarely investigated.In this work,we put forward a novel supramolecular inclusion-based method through introducing two macrocyclic hosts,cucurbit[7]uril(CB[7])and cucurbit[8]uril(CB[8])to facilitate hierarchical assembly of uranyl metallacycles with higher complexity,and successfully prepare two different kinds of uranyl metallacycle-based complexes with intriguing hierarchical structures,a CB[7]-based four-member molec-ular necklace([4]MN)and a CB[8]-involved ring-in-ring supramolecular polymer chain.The results ob-tained here prove the feasibility of supramolecular inclusion for regulating coordination assembly of uranyl metallacycles and related hierarchical structures.It is believed that this method can be used to achieve the construction of actinide coordination assemblies with higher structural complexity.
文献关键词：
中图分类号：
作者姓名：
Yuanyuan Liang;Lei Mei;Qiuyan Jin;Junshan Geng;Jingyang Wang;Kang Liu;Kongqiu Hu;Jipan Yu;Weiqun Shi
作者机构：
Laboratory of Nuclear Energy Chemistry,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100049,China;University of Chinese Academy of Sciences,Beijing 100049,China
文献出处：
引用格式：
[1]Yuanyuan Liang;Lei Mei;Qiuyan Jin;Junshan Geng;Jingyang Wang;Kang Liu;Kongqiu Hu;Jipan Yu;Weiqun Shi-.Hierarchical assembly of uranyl metallacycles involving macrocyclic hosts)[J].中国化学快报（英文版）,2022(07):3539-3542
A类：
metallacycles,Actinide,metallacycle,necklace
B类：
Hierarchical,assembly,uranyl,involving,macrocyclic,hosts,emerging,class,functional,coordination,assemblies,but,multi,level,from,units,toward,hierarchical,supramolecular,structures,still,rarely,investigated,In,this,work,we,put,forward,novel,inclusion,method,through,introducing,two,cucurbit,uril,CB,facilitate,higher,complexity,successfully,prepare,different,kinds,complexes,intriguing,four,member,MN,involved,ring,polymer,chain,results,ob,tained,here,prove,feasibility,regulating,related,It,believed,that,can,used,achieve,construction,actinide,structural
AB值：
0.499327
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