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典型文献
Enhanced photocatalytic hydrogen production under visible light of an organic-inorganic hybrid material based on enzo[1,2-b:4,5-b']dithiophene polymer and TiO2
文献摘要:
Titanium dioxide(TiO2)has been limited in photocatalysis due to its wide band gap(3.2 eV)and lim-ited absorption in the ultraviolet range.Therefore,organic components have been introduced to hybrid with TiO2 for enhanced photocatalytic efficiency under visible light.Here,we report that benzo[1,2-b:4,5-b']dithiophene polymer was an ideal organic material for the preparation of a hybrid material with TiO2.The energy band gap of the resulting hybrid material decreased to 2.9 eV and the photocatalytic hy-drogen production performance reached 745.0 pmol g-1 h-1 under visible light irradiation.Meanwhile,the material still maintained the stability of hydrogen production performance after 40 h of photocat-alytic cycles.The analysis of the transient current response and electrochemical impedance revealed that the main reasons for the enhanced water splitting of the hybrid materials were the faster separation of electron hole pairs and the lower recombination of photocarrier ions.Our findings suggest that poly-thiophene is a promising organic material for exploring hybrid materials with enhanced photocatalytic hydrogen production.
文献关键词:
作者姓名:
Fang Jing;Yanmeng Guo;Bo Li;Yi-Fan Chen;Chunman Jia;Jianwei Li
作者机构:
Hainan Provincial Key Laboratory of Fine Chemicals,Advanced Materials of Tropical Island Resources of Ministry of Education,School of Chemical Engineering and Technology,Hainan University,Haikou 570228,China;MediCity Research Laboratory,University of Turku,Tykistokatu 6,Turku 20520,Finland
引用格式:
[1]Fang Jing;Yanmeng Guo;Bo Li;Yi-Fan Chen;Chunman Jia;Jianwei Li-.Enhanced photocatalytic hydrogen production under visible light of an organic-inorganic hybrid material based on enzo[1,2-b:4,5-b']dithiophene polymer and TiO2)[J].中国化学快报(英文版),2022(03):1303-1307
A类:
enzo
B类:
Enhanced,photocatalytic,hydrogen,production,under,visible,light,inorganic,hybrid,dithiophene,polymer,TiO2,Titanium,dioxide,has,been,limited,photocatalysis,due,its,wide,band,gap,eV,absorption,ultraviolet,range,Therefore,components,have,introduced,enhanced,efficiency,Here,report,that,benzo,was,ideal,preparation,energy,resulting,decreased,performance,reached,pmol,irradiation,Meanwhile,still,maintained,stability,after,cycles,analysis,transient,current,response,electrochemical,impedance,revealed,reasons,water,splitting,materials,were,faster,separation,electron,hole,pairs,lower,recombination,photocarrier,ions,Our,findings,suggest,promising,exploring
AB值:
0.500419
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