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典型文献
Construction and performance of CdS/MoO2@Mo2C-MXene photocatalyst for H2 production
文献摘要:
Nowadays,photocatalytic technologies are regarded as promising strategies to solve energy problems,and various photocatalysts have been synthesized and explored.In this paper,a novel CdS/MoO2@Mo2C-MXene photocatalyst for H2 production was constructed by a two-step hydrothermal method,where MoO2@Mo2C-MXene acted as a binary co-catalyst.In the first hydrothermal step,MoO2 crystals with an egged shape grew on the surface of two-dimensional(2D)Mo2C MXene via an oxidation process in HCl aqueous solution.In the second hydrothermal step,CdS nanorods were uniformly assembled on the surface of MoO2@Mo2C-MXene in ethylenediamine with an inorganic cadmium source and organic sulfur source.The CdS/MoO2@Mo2C-MXene composite with MoO2@Mo2C-MXene of 5 wt%exhibits an ultrahigh visible-light photocatalytic H2 production activity of 22,672 μmol/(g·h),which is~21%higher than that of CdS/Mo2C-MXene.In the CdS/MoO2@Mo2C-MXene composite,the MoO2 with metallic nature separates CdS and Mo2C MXene,which acts as an electron-transport bridge between CdS and Mo2C MXene to accelerate the photoinduced electron transferring.Moreover,the energy band structure of CdS was changed by MoO2@Mo2C-MXene to suppress the recombination of photogenerated carriers.This novel compound delivers upgraded photocatalytic H2 evolution performance and a new pathway of preparing the low-cost photocatalyst to solve energy problems in the future.
文献关键词:
作者姓名:
Sen JIN;Huijuan JING;Libo WANG;Qianku HU;Aiguo ZHOU
作者机构:
School of Materials Science and Engineering,Henan Polytechnic University,Jiaozuo 454003,China
引用格式:
[1]Sen JIN;Huijuan JING;Libo WANG;Qianku HU;Aiguo ZHOU-.Construction and performance of CdS/MoO2@Mo2C-MXene photocatalyst for H2 production)[J].先进陶瓷(英文版),2022(09):1431-1444
A类:
egged
B类:
Construction,performance,CdS,MoO2,Mo2C,MXene,H2,production,Nowadays,photocatalytic,technologies,are,regarded,promising,strategies,solve,energy,problems,various,photocatalysts,have,been,synthesized,explored,In,this,paper,novel,was,constructed,by,two,step,hydrothermal,method,where,acted,binary,first,crystals,shape,grew,surface,dimensional,2D,via,oxidation,process,HCl,aqueous,solution,second,nanorods,were,uniformly,assembled,ethylenediamine,inorganic,cadmium,source,sulfur,composite,wt,exhibits,ultrahigh,visible,light,activity,which,higher,than,that,metallic,nature,separates,acts,electron,transport,bridge,between,accelerate,photoinduced,transferring,Moreover,band,structure,changed,suppress,recombination,photogenerated,carriers,This,compound,delivers,upgraded,evolution,new,pathway,preparing,low,cost,future
AB值:
0.481213
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