典型文献
Fluorine-containing agrochemicals in the last decade and approaches for fluorine incorporation
文献摘要:
In this review,the methodologies for fluorine incorporation of 40 fluorine-containing agrochemicals that received an international standardization organization(ISO)name during the last decade are described.The predominant approach for fluorine introduction of these agrochemicals is to use a fluorine-containing building block.Here we present how the fluorine-containing building blocks are introduced into these agrochemicals.The synthetic methods of fluorine-containing building blocks that are not easily available are also specifically discussed.Fluoroarenes,difluomethylarenes and trifluomethylarenes are the main building blocks that have been used in this review.Fluorine-containing small molecules,such as alcohol,amine,ketoester,olefin are also widely used.The only example of late-stage fluorination is the synthe-sis of fungicide quinofumelin.We believe the fluorine introduction methods described here can provide ideas for the development of new and economical pesticide synthetic routes,and stimulate researchers to develop new fluorine incorporation methods and create new pesticides.
文献关键词:
中图分类号:
作者姓名:
Qiang Wang;Hongjian Song;Qingmin Wang
作者机构:
State Key Laboratory of Elemento-Organic Chemistry,Research Institute of Elemento-Organic Chemistry,College of Chemistry,Frontiers Science Center for New Organic Matter,Nankai University,Tianjin 300071,China;Department of Organic Chemistry,Stockholm University,SE-106 91 Stockholm,Sweden
文献出处:
引用格式:
[1]Qiang Wang;Hongjian Song;Qingmin Wang-.Fluorine-containing agrochemicals in the last decade and approaches for fluorine incorporation)[J].中国化学快报(英文版),2022(02):626-642
A类:
Fluoroarenes,difluomethylarenes,trifluomethylarenes,ketoester,quinofumelin
B类:
Fluorine,containing,agrochemicals,last,decade,approaches,fluorine,incorporation,In,this,review,methodologies,that,received,international,standardization,organization,ISO,name,during,described,predominant,introduction,these,building,Here,we,present,how,blocks,introduced,into,synthetic,methods,not,easily,available,also,specifically,discussed,main,have,been,used,small,molecules,such,alcohol,amine,olefin,widely,only,example,stage,fluorination,sis,fungicide,We,believe,here,can,provide,ideas,development,new,economical,routes,stimulate,researchers,create,pesticides
AB值:
0.466509
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