典型文献
Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries
文献摘要：
Through tailoring interfacial chemistry,elec-trolyte engineering is a facile yet effective strategy for high-performance lithium(Li)metal batteries,where the solva-tion structure is critical for interfacial chemistry.Herein,the effect of electrostatic interaction on regulating an anion-rich solvation is firstly proposed.The moderate electrostatic inter-action between anion and solvent promotes anion to enter the solvation sheath,inducing stable solid electrolyte inter-phase with fast Li+transport kinetics on the anode.This as-designed electrolyte exhibits excellent compatibility with Li metal anode(a Li deposition/stripping Coulombic efficiency of 99.3％)and high-voltage LiCoO2 cathode.Consequently,the 50 μm-thin Lillhigh-loading LiCoO2 cells achieve sig-nificantly improved cycling performance under stringent conditions of high voltage over 4.5 V,lean electrolyte,and wide temperature range(-20 to 60℃).This work inspires a groundbreaking strategy to manipulate the solvation structure through regulating the interactions of solvent and anion for high-performance Li metal batteries.
文献关键词：
中图分类号：
作者姓名：
Junru Wu;Ziyao Gao;Yao Wang;Xu Yang;Qi Liu;Dong Zhou;Xianshu Wang;Feiyu Kang;Baohua Li
作者机构：
Tsinghua Shenzhen International Graduate School,Tsinghua University,Shenzhen 518055,People's Republic of China;School of Materials Science and Engineering,Tsinghua University,Beijing 100084,People's Republic of China;College of Materials Science and Engineering,Hunan University,Changsha 410082,People's Republic of China
文献出处：
引用格式：
[1]Junru Wu;Ziyao Gao;Yao Wang;Xu Yang;Qi Liu;Dong Zhou;Xianshu Wang;Feiyu Kang;Baohua Li-.Electrostatic Interaction Tailored Anion-Rich Solvation Sheath Stabilizing High-Voltage Lithium Metal Batteries)[J].纳微快报（英文）,2022(09):147-159
A类：
solva,Lillhigh
B类：
Electrostatic,Interaction,Tailored,Anion,Rich,Solvation,Sheath,Stabilizing,High,Voltage,Lithium,Metal,Batteries,Through,tailoring,interfacial,chemistry,engineering,facile,yet,effective,strategy,performance,lithium,metal,batteries,where,structure,critical,Herein,electrostatic,regulating,anion,rich,solvation,firstly,proposed,moderate,between,solvent,promotes,enter,sheath,inducing,stable,solid,electrolyte,phase,fast,Li+transport,kinetics,anode,This,designed,exhibits,excellent,compatibility,deposition,stripping,Coulombic,efficiency,voltage,LiCoO2,cathode,Consequently,thin,loading,cells,achieve,nificantly,improved,cycling,under,stringent,conditions,over,lean,wide,temperature,range,work,inspires,groundbreaking,manipulate,through,interactions
AB值：
0.617651
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