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典型文献
A Stretchable Ionic Conductive Elastomer for High-Areal-Capacity Lithium-Metal Batteries
文献摘要:
Developing high-areal-capacity and dendrite-free lithium(Li)anodes is of significant importance for the practical applications of the Li-metal secondary batteries.Herein,an effective strategy to stabilize the high-areal-capacity Li electrodeposition by modifying the Li metal with a stretchable ionic conductive elastomer(ICE)is demonstrated.The ICE layer prepared via an instant photocuring process shows a promising Li+-ion conductivity at room temperature.When being used in Li-metal batteries,the thin ICE coating(~0.27 pm)acts as both a stretchable constraint to minimize the Li loss and a protective layer to facilitate the uniform flux of Li ions.With this ICE-modifying strategy,the reversibility and cyclability of the Li anodes under high-areal-capacity condition in carbonate electrolyte are significantly improved,leading to a stable Li stripping/plating for 500 h at an ultrahigh areal capacity of 20 mAh cm-2 in commercial carbonate electrolyte.When coupled with industry-level thick LiFePO4 electrodes(20.0 mg cm-2),the cells with ICE-Li anodes show significantly enhanced rate and cycling capability.
文献关键词:
作者姓名:
Kejia Li;Zhenglu Zhu;Ruirui Zhao;Haoran Du;Xiaoqun Qi;Xiaobin Xu;Long Qie
作者机构:
Institute of New Energy for Vehicles,School of Materials Science and Engineering,Tongji University,Shanghai 201804,China
引用格式:
[1]Kejia Li;Zhenglu Zhu;Ruirui Zhao;Haoran Du;Xiaoqun Qi;Xiaobin Xu;Long Qie-.A Stretchable Ionic Conductive Elastomer for High-Areal-Capacity Lithium-Metal Batteries)[J].能源与环境材料(英文),2022(01):337-343
A类:
Areal
B类:
Stretchable,Ionic,Conductive,Elastomer,High,Capacity,Lithium,Metal,Batteries,Developing,areal,capacity,dendrite,free,lithium,anodes,importance,practical,applications,metal,secondary,batteries,Herein,effective,strategy,stabilize,electrodeposition,by,modifying,stretchable,ionic,conductive,elastomer,ICE,demonstrated,layer,prepared,via,instant,photocuring,process,shows,promising,Li+,conductivity,room,temperature,When,being,used,thin,coating,pm,acts,both,constraint,minimize,loss,protective,facilitate,uniform,flux,With,this,reversibility,cyclability,under,condition,carbonate,electrolyte,significantly,improved,leading,stable,stripping,plating,ultrahigh,mAh,commercial,coupled,industry,level,thick,LiFePO4,electrodes,cells,enhanced,cycling,capability
AB值:
0.602293
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