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典型文献
Hierarchically Micro/Nanostructured Current Collectors Induced by Ultrafast Femtosecond Laser Strategy for High-Performance Lithium-ion Batteries
文献摘要:
Commercial Cu and Al current collectors for lithium-ion batteries(LIBs)possess high electrical conductivity,suitable chemical and electrochemical stability.However,the relatively flat surface of traditional current collectors causes weak bonding strength and poor electrochemical contact between current collectors and electrode materials,resulting in potential detachment of active materials and rapid capacity degradation during extended cycling.Here,we report an ultrafast femtosecond laser strategy to manufacture hierarchical micro/nanostructures on commercial Al and Cu foils as current collectors for high-performance LIBs.The hierarchically micro/nanostructured current collectors(HMNCCs)with high surface area and roughness offer strong adhesion to active materials,fast electronic delivery of entire electrodes,significantly improving reversible capacities and cyclic stability of HMNCCs based LIBs.Consequently,LiNi0.5Co0.2Mn0.302(NCM523)cathode with Al HMNCC generated a high reversible capacity after 200 cycles(25%higher than that of cathode with Al CC).Besides,graphite anode with Cu HMNCC also maintained prominent reversible capacity even after 600 cycles.Moreover,the full cell assembled by graphite anode with Cu HMNCC and NCM523 cathode with Al HMNCC achieved high reversible capacity and remarkable cycling stability under industrial-grade mass loading.This study provides promising candidate for achieving high-performance LIBs current collectors.
文献关键词:
作者姓名:
Yaya Wang;Zexu Zhao;Jiang Zhong;Tao Wang;Lei Wang;Hanjiao Xu;Jinhui Cao;Jinhao Li;Guanhua Zhang;Huilong Fei;Jian Zhu
作者机构:
State Key Laboratory for Chemo/Biosensing and Chemometrics,College of Chemistry and Chemical Engineering,Hunan Key Laboratory of Two-Dimensional Materials,Engineering Research Center of Advanced Catalysis,Ministry of Education,Hunan University,Changsha 410082,China;State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body,Hunan Provincial Key Laboratory of Intelligent Laser Manufacturing,Hunan University,Changsha 410082,China;College of Mechanical and Vehicle Engineering,Hunan University,Changsha 410082,China
引用格式:
[1]Yaya Wang;Zexu Zhao;Jiang Zhong;Tao Wang;Lei Wang;Hanjiao Xu;Jinhui Cao;Jinhao Li;Guanhua Zhang;Huilong Fei;Jian Zhu-.Hierarchically Micro/Nanostructured Current Collectors Induced by Ultrafast Femtosecond Laser Strategy for High-Performance Lithium-ion Batteries)[J].能源与环境材料(英文),2022(03):969-976
A类:
Collectors,HMNCCs,HMNCC
B类:
Hierarchically,Micro,Nanostructured,Current,Induced,by,Ultrafast,Femtosecond,Laser,Strategy,High,Performance,Lithium,Batteries,Commercial,current,collectors,lithium,batteries,LIBs,possess,electrical,conductivity,suitable,electrochemical,stability,However,relatively,flat,surface,traditional,causes,weak,bonding,strength,poor,contact,between,materials,resulting,potential,detachment,active,rapid,capacity,degradation,during,extended,cycling,Here,report,ultrafast,femtosecond,laser,strategy,manufacture,micro,nanostructures,commercial,foils,performance,hierarchically,nanostructured,area,roughness,offer,strong,adhesion,electronic,delivery,entire,electrodes,significantly,improving,reversible,capacities,cyclic,Consequently,LiNi0,5Co0,2Mn0,NCM523,cathode,generated,after,cycles,higher,than,that,Besides,graphite,anode,also,maintained,prominent,even,Moreover,full,cell,assembled,achieved,remarkable,under,industrial,grade,mass,loading,This,study,provides,promising,candidate,achieving
AB值:
0.576341
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